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Variable Host–Guest Charge-Transfer Interactions in 1D Channels Formed in a Molecule-Based Honeycomb Lattice of Phenazine Analogue of Triptycene

Ushiroguchi, Ryo Shuku, Yoshiaki Suizu, Rie Awaga, Kunio 名古屋大学

2020.12.02

概要

We synthesized a phenazine analogue of triptycene acceptor, Trip-Phz, and found a honeycomb network of Trip-Phz with a wide 1D channel running through it. The interior surface of this channel was covered by the π electrons of Trip-Phz. Even though there was no interaction between Trip-Phz and an organic donor, tetrathiafulvalene (TTF), in their solutions, the honeycomb crystals of Trip-Phz exhibited a host–guest charge-transfer (CT) interaction with TTF, specifically a reversible adsorption/desorption of TTF with the appearance/disappearance of a CT band.

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