1. Omer, A. M. Energy, environment and sustainable development. Renew. Sustain. Energy Rev. 12, 2265–2300 (2008).
2. Calm, J. M. The next generation of refrigerants—Historical review, considerations, and outlook. Int. J. Refrig. 31, 1123–1133 (2008).
3. The Importance of Energy Efficiency in the Refrigeration and Heat Pump Sectors. United Nations Environment Programme, Briefing
Note A (2018).
4. Gschneidner, A., Pecharsky, V. K. & Tsokol, A. O. Recent developments in magnetocaloric materials. Reports Prog. Phys. 68,
1479–1539 (2005).
5. Shen, B. G., Sun, J. R., Hu, F. X., Zhang, H. W. & Cheng, Z. H. Recent progress in exploring magnetocaloric materials. Adv. Mater.
21, 4545–4564 (2009).
6. Valant, M. Electrocaloric materials for future solid-state refrigeration technologies. Prog. Mater. Sci. 57, 980–1009 (2012).
7. Fähler, S. et al. Caloric effects in ferroic materials: New concepts for cooling. Energy Technol. 14, 10–19 (2012).
8. Moya, X., Kar-Narayan, S. & Mathur, N. D. Caloric materials near ferroic phase transitions. Nat. Mater. 13, 439–450 (2014).
9. Mañosa, L. & Planes, A. Materials with giant mechanocaloric effects: Cooling by strength. Adv. Mater. 29, 1603607 (2017).
10. Franco, V., Blázquez, J. S., Ingale, B. & Conde, A. The magnetocaloric effect and magnetic refrigeration near room temperature:
Materials and models. Annu. Rev. Mater. Res. 42, 305–342 (2012).
11. Brown, G. V. Magnetic heat pumping near room temperature. J. Appl. Phys. 47, 3673–3680 (1976).
12. Mizumaki, M. et al. Magnetocaloric effect of field-induced ferromagnet B
aFeO3. J. Appl. Phys. 114, 073901 (2013).
13. Pecharsky, V. K. & Gschneidner, K. A. Giant magnetocaloric effect in Gd5(Si2Ge2). Phys. Rev. Lett. 78, 4494–4497 (1997).
14. Stern-Taulats, E. et al. Barocaloric and magnetocaloric effects in F
e49Rh51. Phys. Rev. B 89, 214105 (2014).
15. Fujita, A., Fujieda, S., Hasegawa, Y. & Fukamichi, K. Itinerant-electron metamagnetic transition and large magnetocaloric effects
in La(FexSi1−x)13 compounds and their hydrides. Phys. Rev. B 67, 104416 (2003).
16. Numazawa, T., Kamiya, K., Utaki, T. & Matsumoto, K. Magnetic refrigerator for hydrogen liquefaction. Cryogenics (Guildf) 62,
185 (2014).
17. Park, J., Jeong, S. & Park, I. Development and parametric study of the convection-type stationary adiabatic demagnetization
refrigerator (ADR) for hydrogen re-condensation. Cryogenics (Guildf) 71, 82 (2015).
18. McMichae, R. D., Ritter, J. J. & Shull, R. D. Enhanced magnetocaloric effect in G
d3Ga5−xFexO12. J. Appl. Phys. 733, 6946 (2006).
19. Li, L. et al. Magnetic properties and excellent cryogenic magnetocaloric performances in B-site ordered RE2ZnMnO6 (RE = Gd,
Dy and Ho) perovskites. Acta Mater. 194, 354 (2020).
20. Li, L. & Yan, M. Recent progresses in exploring the rare earth based intermetallic compounds for cryogenic magnetic refrigeration.
J. Alloys Compd. 823, 153810 (2020).
21. Moya, X. et al. Giant electrocaloric strength in single-crystal B
aTiO3. Adv. Mater. 25, 1360–1365 (2013).
22. Mischenko, A. S., Zhang, Q., Scott, J. F., Whatmore, R. W. & Mathur, N. D. Giant electrocaloric effect in thin-film PbZr0.95Ti0.05O3.
Science (80–.) 311, 1270 (2006).
23. Nair, B. et al. Large electrocaloric effects in oxide multilayer capacitors over a wide temperature range. Nature 575, 468–472 (2019).
24. Matsunami, D. & Fujita, A. Electrocaloric effect of metal-insulator transition in VO2. Appl. Phys. Lett. 106, 042901 (2015).
25. Mañosa, L. et al. Giant solid-state barocaloric effect in the Ni–Mn–In magnetic shape-memory alloy. Nat. Mater. 9, 478–481 (2010).
26. Stern-Taulats, E. et al. Inverse barocaloric effects in ferroelectric B
aTiO3 ceramics. APL Mater. 4, 091102 (2016).
27. Mikhaleva, E. A. et al. Caloric characteristics of P
bTiO3 in the temperature range of the ferroelectric phase transition. Phys. Solid
State 54, 1832–1840 (2012).
28. Stern-Taulats, E. et al. Multicaloric materials and effects. MRS Bull. 43, 295–299 (2018).
29. Czernuszewicz, A., Kaleta, J. & Lewandowski, D. Multicaloric effect: Toward a breakthrough in cooling technology. Energy Convers.
Manag. 178, 335–342 (2018).
30. Vasil’ev, A. & Yolkova, O. New functional materials AC3B4O12. Low Temp. Phys. 33, 895 (2007).
31. Shimakawa, Y. A-site-ordered perovskites with intriguing physical properties. Inorg. Chem. 47, 8562–8570 (2008).
32. Etter, M. et al. Charge disproportionation of mixed-valent Cr triggered by Bi lone-pair effect in the A-site-ordered perovskite
BiCu3Cr4O12. Phys. Rev. B 97, 195111 (2018).
33. Long, Y. W. et al. Temperature-induced A-B intersite charge transfer in an A-site-ordered LaCu3Fe4O12 perovskite. Nature 458,
60–63 (2009).
Scientific Reports |
(2021) 11:12682 |
https://doi.org/10.1038/s41598-021-91888-8
Vol.:(0123456789)
www.nature.com/scientificreports/
A Self-archived copy in
Kyoto University Research Information Repository
https://repository.kulib.kyoto-u.ac.jp
34. Long, Y. et al. Intermetallic charge transfer in A-site-ordered double perovskite B
iCu3Fe4O12. Inorg. Chem. 48, 8489 (2009).
35. Shimakawa, Y. Crystal and magnetic structures of CaCu3Fe4O12 and LaCu3Fe4O12: Distinct charge transitions of unusual high
valence Fe. J. Phys. D Appl. Phys. 48, 504006 (2015).
36. Shimakawa, Y. & Mizumaki, M. Multiple magnetic interactions in A-site-ordered perovskite-structure oxides. J. Phys. Condens.
Matter 26, 473203 (2014).
37. Kosugi, Y. et al. Colossal barocaloric effect by large latent heat produced by first-order intersite-charge-transfer transition. Adv.
Funct. Mater. https://doi.org/10.1002/adfm.202009476 (2021).
38. Lashley, J. C. et al. Critical examination of heat capacity measurements made on a quantum design physical property measurement
system. Cryogenics (Guildf) 43, 369–378 (2003).
39. Giguére, A. et al. Direct measurement of the “giant” adiabatic temperature change in G
d5Si2Ge2s. Phys. Rev. Lett. 83, 2262–2265
(1999).
40. Liu, G. J. et al. Determination of the entropy changes in the compounds with a first-order magnetic transition. Appl. Phys. Lett.
90, 1–4 (2007).
41. Provenzano, V., Shapiro, A. J. & Shull, R. D. Reduction of hysteresis losses in the magnetic refrigerant Gd5Ge2Si2 by the addition
of iron. Nature 429, 853 (2004).
42. Zhang, H. et al. Reduction of hysteresis loss and large magnetocaloric effect in the C- and H-doped La(Fe, Si)13 compounds around
room temperature. J. Appl. Phys. 111, 07A909 (2012).
43. Stern-Taulats, E. et al. Giant multicaloric response of bulk Fe49Rh51. Phys. Rev. B 95, 104424 (2017).
44. Izumi, F. & Momma, K. Three-dimensional visualization in powder diffraction. Solid State Phenom. 130, 15–20 (2007).
45. Momma, K. & Izumi, F. VESTA: A three-dimensional visualization system for electronic and structural analysis. J. Appl. Crystallogr. 41, 653–658 (2008).
46. Matsunami, D., Fujita, A., Takenaka, K. & Kano, M. Giant barocaloric effect enhanced by the frustration of the antiferromagnetic
phase in M
n3GaN. Nat. Mater. 14, 73–78 (2015).
Acknowledgements
We thank Shoubao Zhang and Takashi Saito for discussion, and Shogo Kawaguchi for help in synchrotron X-ray
diffraction measurements. The synchrotron radiation experiments were performed at the Japan Synchrotron
Radiation Research Institute, Japan (Proposal Nos. 2019B1757, 2020A1137 and 2020A1671). This work was partly
supported by Grants-in-Aid for Scientific Research (Nos. 24540362, 19K15585, 19H05823, 19K22073, 20K20547,
20H02829, and 20H00397) and by grants for the Integrated Research Consortium on Chemical Sciences and the
International Collaborative Research Program of Institute for Chemical Research in Kyoto University from the
Ministry of Education, Culture, Sports, Science and Technology (MEXT) of Japan. This work was also supported
by the Japan Society for the Promotion of Science Core-to-Core Program (A) Advanced Research Networks and
by the Yazaki Memorial Foundation for Science and Technology.
Author contributions
Y.K. and Y.S. conceived the idea and initiated the project. D.K., A.F., H.T., and Y.S. supervised the project. Y.K.,
M.G., Z.T., and M.I. prepared the samples and performed structure analysis as well as magnetic and property
measurements. Y.K., M.G., K.Y., M.M., A.F., and Y.S. measured caloric effects. All authors discussed the experimental data and wrote the manuscript.
Competing interests The authors declare no competing interests.
Additional information
Supplementary Information The online version contains supplementary material available at https://doi.org/
10.1038/s41598-021-91888-8.
Correspondence and requests for materials should be addressed to Y.S.
Reprints and permissions information is available at www.nature.com/reprints.
Publisher’s note Springer Nature remains neutral with regard to jurisdictional claims in published maps and
institutional affiliations.
Open Access This article is licensed under a Creative Commons Attribution 4.0 International
License, which permits use, sharing, adaptation, distribution and reproduction in any medium or
format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the
Creative Commons licence, and indicate if changes were made. The images or other third party material in this
article are included in the article’s Creative Commons licence, unless indicated otherwise in a credit line to the
material. If material is not included in the article’s Creative Commons licence and your intended use is not
permitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from
the copyright holder. To view a copy of this licence, visit http://creativecommons.org/licenses/by/4.0/.
© The Author(s) 2021
Scientific Reports |
Vol:.(1234567890)
(2021) 11:12682 |
https://doi.org/10.1038/s41598-021-91888-8
...
論文の公開元へ
