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Chemical modification utilizing a terminal structure exposed on the specific surface of polymer-metal complex nanocrystals

Ryuju Suzuki Tsunenobu Onodera Hitoshi Kasai Hidetoshi Oikawa 東北大学 DOI:10.1039/C9RA10244B

2020.02

概要

It has been difficult to selectively modify the surface of molecular crystals by chemical reactions because they usually have no reaction points on their surfaces. In this paper, focusing on the unique nanocrystal surface of the polymer metal complex (PMC) [{Cu2(m-Br)2(PPh3)2}(m-bpy)]n having an exposed reactive terminal chain, we successfully modified the surface of PMC nanocrystals (NCs) through an alkylation reaction. Interestingly, after the alkylation reaction, the luminescence spectrum of PMC NCs blue- shifted, and the luminescence quantum yield increased. PMC NCs with a large specific surface area showed optically peculiar or characteristic properties compared with the corresponding bulk crystals. PMC NCs have high potential as a new class of luminescent materials due to their surface effect.

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参考文献

1 H. Araki, K. Tsuge, Y. Sasaki, S. Ishizaka and N. Kitamura, Inorg. Chem., 2005, 44, 9667–9675.

2 R. Suzuki, T. Onodera, S. Deguchi, H. Kasai and H. Oikawa, J. Taiwan Inst. Chem. Eng., 2018, 92, 129–133.

3 R. Suzuki, T. Onodera, H. Kasai and H. Oikawa, RSC Adv., 2018, 8, 16406–16409.

4 R. Suzuki, T. Onodera, H. Kasai and H. Oikawa, Jpn. J. Appl. Phys., 2014, 53, 06JH03.

5 R. Suzuki, T. Onodera, H. Kasai and H. Oikawa, Mol. Cryst. Liq. Cryst., 2015, 621, 150–155.

6 R. Suzuki, T. Onodera, H. Kasai and H. Oikawa, Mol. Cryst. Liq. Cryst., 2017, 654, 109–114.

7 Y. Fujiki, N. Tokunaga, S. Shinkai and K. Sada, Angew. Chem., Int. Ed., 2006, 45, 4764–4767.

8 T. Kondo, S. Aoshima, K. Hirata, K. Honda, Y. Einaga, A. Jujishima and T. Kawai, Langmuir, 2008, 24, 7545–7548.

9 Y. Fujiki, S. Sihinkai and K. Sada, Cryst. Growth Des., 2009, 9, 2745–2755.

10 S. H. Yoo, T. Eon, S. Kwon, J. Gong, J. Kim, S. J. Cho, R. W. Driver, Y. Lee, H. Kim and H. Lee, J. Am. Chem. Soc., 2015, 137, 2159–2162.

11 N. Menschutkin, Z. Physiol. Chem., 1890, 5, 589–600.

12 C. R. Noller and R. Dinsmore, J. Am. Chem. Soc., 1932, 54, 1025–1034.

13 E. M. Kosower and J. L. Cotter, J. Am. Chem. Soc., 1964, 86, 5524–5527.

14 F. N. Jones, M. E. Nichols and S. P. Pappas, Organic Coatings: Science and Technology, Wiley, New York, 2007.

15 N. C. Anderson, M. P. Hendricks, J. J. Choi and J. S. Owen, J. Am. Chem. Soc., 2013, 135, 18536–18548.

16 P. R. Brown, D. Kim, R. R. Lunt, N. Zhao, M. G. Bawendi, J. C. Grossman and V. Bulovic, ACS Nano, 2014, 8, 5863– 5872.

17 S. Yang, F. Liu, C. Wu and S. Yang, Small, 2016, 30, 4028– 4047.

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