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大学・研究所にある論文を検索できる 「Control of supramolecular organizations by coordination bonding in tetrapyridylporphyrin thin films」の論文概要。リケラボ論文検索は、全国の大学リポジトリにある学位論文・教授論文を一括検索できる論文検索サービスです。
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Control of supramolecular organizations by coordination bonding in tetrapyridylporphyrin thin films

Tomita, Kazutaka Shioya, Nobutaka Shimoaka, Takafumi Wakioka, Masayuki Hasegawa, Takeshi 京都大学 DOI:10.1039/d1cc06169k

2022.02

概要

Coordination bonding has been employed for the first time to control molecular orientation in thin films and is demonstrated by using tetrapyridylporphyrin. Changing the central metal ion of porphyrin controls the balance of the coordination bonding and hydrogen bonding, and edge-on orientation has been realized for the first time as well as face-on orientation. The mechanism of the film structure formation is comprehensively explained based on the electron configuration of the central metal ion.

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