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大学・研究所にある論文を検索できる 「Effect of introducing a cyclobutylmethyl group into an onium cation on the thermodynamic properties of ionic clathrate hydrates」の論文概要。リケラボ論文検索は、全国の大学リポジトリにある学位論文・教授論文を一括検索できる論文検索サービスです。

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Effect of introducing a cyclobutylmethyl group into an onium cation on the thermodynamic properties of ionic clathrate hydrates

Azuma, Sakura 大阪大学

2023.01.07

概要

In order to achieve the efficient utilization of thermal
energy, the development of a latent heat storage technology is
absolutely essential. The latent heat storage technology is a
method of thermal storage using the enthalpy of phase
transition of the latent heat storage materials.1-3 For the latent
heat storage materials, water,1-3 paraffin,3,4 and molten salt4,5
have been well known. Ionic clathrate hydrate (ICH) is also one
of the promising thermal storage materials, especially, suitable
for being utilized as thermal energy in a temperature range of
273 – 300 K.6-9
ICH is a crystalline inclusion compound composed of
hydrogen-bonded
water
molecules
and
quaternary
alkylammonium or alkylphosphonium salts. 8-12 ICHs have the
equilibrium temperatures around 270 – 300 K with the
dissociation enthalpies around 200 J·g−1.6-10,13-22 The
thermodynamic properties including the equilibrium
temperature and the dissociation enthalpy can be adjusted by
choosing the appropriate guest species. ...

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