1 M. Y. Versavel and J. A. Haber, “Structural and optical properties of amorphous and crystalline antimony sulfide thin-films,” Thin Solid Films 515(18), 7171–7176 (2007).
2 R. Kondrotas, C. Chen, and J. Tang, “Sb S solar cells,” Joule 2(5), 857–878
3 J. Han, X. Pu, H. Zhou, Q. Cao, S. Wang, Z. He, B. Gao, T. Li, J. Zhao, and X. Li, “Synergistic effect through the introduction of inorganic zinc halides at the interface of TiO2 and Sb2S3 for high-performance Sb2S3 planar thin-film solar cells,” ACS Appl. Mater. Interfaces 12(39), 44297–44306 (2020).
4 L. Wang, D. Li, K. Li, C. Chen, H. Deng, L. Gao, Y. Zhao, F. Jiang, L. Li, F. Huang, Y. He, H. Song, G. Niu, and J. Tang, “Stable 6%-efficient Sb2Se3 solar cells with a ZnO buffer layer,” Nat. Energy 2(4), 1–9 (2017).
5 X. Wen, C. Chen, S. Lu, K. Li, R. Kondrotas, Y. Zhao, W. Chen, L. Gao, C. Wang, and J. Zhang, “Vapor transport deposition of antimony selenide thin film solar cells with 7.6% efficiency,” Nat. Commun. 9(1), 2179 (2018).
6 H. Deng, Y. Zeng, M. Ishaq, S. Yuan, H. Zhang, X. Yang, M. Hou, U. Farooq, J. Huang, K. Sun, R. Webster, H. Wu, Z. Chen, F. Yi, H. Song, X. Hao, and J. Tang, “Quasiepitaxy strategy for efficient full-inorganic Sb2S3 solar cells,” Adv. Funct. Mater. 29(31), 1901720 (2019).
7 R. Nie, H. S. Yun, M. J. Paik, A. Mehta, B. W. Park, Y. C. Choi, and S. I. Seok, “Efficient solar cells based on light-harvesting antimony sulfoiodide,” Adv. Energy Mater. 8(7), 1701901 (2018).
8 R. Tang, X. Wang, C. Jiang, S. Li, W. Liu, H. Ju, S. Yang, C. Zhu, and T. Chen, “n-type doping of Sb2S3 light-harvesting films enabling high-efficiency planar heterojunction solar cells,” ACS Appl. Mater. Interfaces 10(36), 30314–30321 (2018).
9 Z. Li, X. Liang, G. Li, H. Liu, H. Zhang, J. Guo, J. Chen, K. Shen, X. San, W. Yu, R. Schropp, and Y. Mai, “9.2%-efficient core-shell structured antimony selenide nanorod array solar cells,” Nat. Commun. 10(1), 125 (2019).
10 Y. Zeng, K. Sun, J. Huang, M. P. Nielsen, F. Ji, C. Sha, S. Yuan, X. Zhang, C. Yan, X. Liu, H. Deng, Y. Lai, J. Seidel, N. Ekins-Daukes, F. Liu, H. Song, M. Green, and X. Hao, “Quasi-vertically-orientated antimony sulfide inorganic thin-film solar cells achieved by vapor transport deposition,” ACS Appl. Mater. Interfaces 12(20), 22825–22834 (2020).
11 S.-J. Lee, S.-J. Sung, K.-J. Yang, J.-K. Kang, J. Y. Kim, Y. S. Do, and D.-H. Kim, “Approach to transparent photovoltaics based on wide band gap Sb2S3 absorber layers and optics-based device optimization,” ACS Appl. Energy Mater. 3(12), 12644–12651 (2020).
12 X. Jin, Y. Fang, T. Salim, M. Feng, S. Hadke, S. W. Leow, T. C. Sum, and L. H. Wong, “In situ growth of [hk1]-oriented Sb2S3 for solution-processed planar heterojunction solar cell with 6.4% efficiency,” Adv. Funct. Mater. 30(35), 2002887 (2020).
13 W. Lin, W.-T. Guo, L. Yao, J. Li, L. Lin, J.-M. Zhang, S. Chen, and G. Chen, “Zn(O,S) buffer layer for in situ hydrothermal Sb2S3 planar solar cells,” ACS Appl. Mater. Interfaces 13(38), 45726–45735 (2021).
14 W. Wang, X. Wang, G. Chen, L. Yao, X. Huang, T. Chen, C. Zhu, S. Chen, Z. Huang, and Y. Zhang, “Over 6% certified Sb2(S,Se)3 solar cells fabricated via in situ hydrothermal growth and postselenization,” Adv. Electron. Mater. 5(2), 1800683 (2018). 426–431 (2010).
15 Y. Zhao, S. Wang, C. Jiang, C. Li, P. Xiao, R. Tang, J. Gong, G. Chen, T. Chen, and J. Li, “Regulating energy band alignment via alkaline metal fluoride assisted solution post-treatment enabling Sb2(S,Se)3 solar cells with 10.7% efficiency,” Adv. Energy Mater. 12(1), 2103015 (2022).
16 U. A. Shah, S. Chen, G. M. G. Khalaf, Z. Jin, and H. Song, “Wide bandgap Sb2S3 solar cells,” Adv. Funct. Mater. 31(27), 2100265 (2021).
17 J. A. Christians, D. T. Leighton, and P. V. Kamat, “Rate limiting interfacial hole transfer in Sb2S3 solid-state solar cells,” Energy Environ. Sci. 7(3), 1148–1158 (2014).
18 M. Batmunkh, T. J. Macdonald, C. J. Shearer, M. Bat-Erdene, Y. Wang, M. J. Biggs, I. P. Parkin, T. Nann, and J. G. Shapter, “Carbon nanotubes in TiO2 nanofiber photoelectrodes for high-performance perovskite solar cells,” Adv. Sci. 4(4), 1600504 (2017).
19 L. E. Greene, M. Law, B. D. Yuhas, and P. Yang, “ZnO−TiO2 core−shell nanorod/P3HT solar cells,” J. Phys. Chem. C 111(50), 18451–18456 (2007).
20 Y.-J. Lee, D. S. Ruby, D. W. Peters, B. B. McKenzie, and J. W. P. Hsu, “ZnO nanostructures as efficient antireflection layers in solar cells,” Nano Lett. 8(5), 1501–1505 (2008).
21 Y. Hames, Z. Alpaslan, A. Kösemen, S. E. San, and Y. Yerli, “Electrochemically 2 3 (2018). grown ZnO nanorods for hybrid solar cell applications,” Solar Energy 84(3),
22 D. Y. Son, J. H. Im, H. S. Kim, and N. G. Park, “11% efficient perovskite solar cell based on ZnO nanorods: An effective charge collection system,” J. Phys. Chem. C 118(30), 16567–16573 (2014).
23 E. Galoppini, J. Rochford, H. Chen, G. Saraf, Y. Lu, A. Hagfeldt, and G. Boschloo, “Fast electron transport in metal organic vapor deposition grown dye-sensitized ZnO nanorod solar cells,” J. Phys. Chem. B 110(33), 16159–16161 (2006).
24 K. Mahmood, A. Khalid, S. W. Ahmad, and M. T. Mehran, “Indium-doped ZnO mesoporous nanofibers as efficient electron transporting materials for perovskite solar cells,” Surf. Coat. Technol. 352, 231–237 (2018).
25 G. S. Han, H. S. Chung, D. H. Kim, B. J. Kim, J.-W. Lee, N.-G. Park, I. S. Cho, J.-K. Lee, S. Lee, and H. S. Jung, “Epitaxial 1D electron transport layers for high- performance perovskite solar cells,” Nanoscale 7(37), 15284–15290 (2015).
26 L. Yang and W. W.-F. Leung, “Application of a bilayer TiO2 nanofiber photoan- ode for optimization of dye-sensitized solar cells,” Adv. Mater. 25(12), 1792–1795 (2013).
27 F. J. Ramos, M. Oliva-Ramirez, M. K. Nazeeruddin, M. Grätzel, A. R. González-Elipe, and S. Ahmad, “Nanocolumnar 1-dimensional TiO2 photoanodes deposited by PVD-OAD for perovskite solar cell fabrication,” J. Mater. Chem. A 3(25), 13291–13298 (2015).
28 L. Yang and W. W.-F. Leung, “Application of a bilayer TiO2 nanofiber photoan- ode for optimization of dye-sensitized solar cells,” Adv. Mater. 23(39), 4559–4562 (2011).
29 C. Ying, F. Guo, Z. Wu, K. Lv, and C. Shi, “Influence of surface modifier molecular structures on the photovoltaic performance of Sb2S3-sensitized TiO2 nanorod array solar cells,” Energy Technol. 8(6), 1901368 (2020).
30 Z. Sun, Z. Peng, Z. Liu, J. Chen, W. Li, W. Qiu, and J. Chen, “Band energy modulation on Cu-doped Sb2S3-based photoelectrodes for charge generation and transfer property of quantum dot–sensitized solar cells,” J. Nanoparticle Res. 22(9), 1–9 (2020).
31 R. Parize, A. Katerski, I. Gromyko, L. Rapenne, H. Roussel, E. Kärber, E. Appert, M. Krunks, and V. Consonni, “ZnO/TiO2/Sb2S3 core–shell nanowire heterostruc- ture for extremely thin absorber solar cells,” J. Phys. Chem. C 121(18), 9672–9680 (2017).
32 Y. Li, Y. Wei, K. Feng, Y. Hao, J. Pei, and B. Sun, “Preparation of Sb2S3 nanocrystals modified TiO2 dendritic structure with nanotubes for hybrid solar cell,” Mater. Res. Express 5(6), 065903 (2018).
33 Y. Li, Y. Wei, K. Feng, Y. Hao, J. Pei, Y. Zhang, and B. Sun, “Introduction of PCPDTBT in P3HT: Spiro-OMeTAD blending system for solid-state hybrid solar cells with dendritic TiO2/Sb2S3 nanorods composite film,” J. Solid State Chem. 276, 278–284 (2019).
34 B. Zhou, T. Hayashi, K. Hachiya, and T. Sagawa, “Preparation of Sb2S3 nanorod arrays by hydrothermal method as light absorbing layer for Sb2S3-based solar cells,” Thin Solid Films 757, 139389 (2022).
35 R. Chen, J. Cao, Y. Duan, Y. Hui, T. T. Chuong, D. Ou, F. Han, F. Cheng, X. Huang, B. Wu, and N. Zheng, “High-efficiency, hysteresis-less, UV-stable per- ovskite solar cells with cascade ZnO–ZnS electron transport layer,” J. Am. Chem. Soc. 141(1), 541–547 (2019).
36 S. Messina, M. T. S. Nair, and P. K. Nair, “All-chemically deposited solar cells with antimony sulfide-selenide/lead sulfide thin film absorbers,” MRS Online Proc. Libr. 1012, 413–418 (2007).
37 Q. Han, L. Chen, M. Wang, X. Yang, L. Lu, and X. Wang, “Low-temperature synthesis of uniform Sb2S3 nanorods and its visible-light-driven photocatalytic activities,” Mater. Sci. Eng., B 166(1), 118–121 (2010).
38 B. Jia and L. Gao, “Growth of well-defined cubic hematite single crystals: Ori- ented aggregation and Ostwald ripening,” Cryst. Growth Des. 8(4), 1372–1376 (2008).
39 I. A. Safo, M. Werheid, C. Dosche, and M. Oezaslan, “The role of polyvinyl- pyrrolidone (PVP) as a capping and structure-directing agent in the formation of Pt nanocubes,” Nanoscale Adv. 1(8), 3095–3106 (2019).
40 G.-X. Liang, Z.-H. Zheng, P. Fan, J.-T. Luo, J.-G. Hu, X.-H. Zhang, H.-L. Ma, B. Fan, Z.-K. Luo, and D.-P. Zhang, “Thermally induced structural evolution and performance of Sb2Se3 films and nanorods prepared by an easy sputtering method,” Sol. Energy Mater. Sol. Cells 174, 263–270 (2018).
41 Q. Wang, Z. Chen, J. Wang, Y. Xu, Y. Wei, Y. Wei, L. Qiu, H. Lu, Y. Ding, and J. Zhu, “Sb2S3 solar cells: Functional layer preparation and device performance,” Inorg. Chem. Front. 6(12), 3381–3397 (2019).
42 T. J. Whittles, T. D. Veal, C. N. Savory, A. W. Welch, F. W. de Souza Lucas, J. T. Gibbon, M. Birkett, R. J. Potter, D. O. Scanlon, A. Zakutayev, and V. R. Dhanak, “Core levels, band alignments, and valence-band states in CuSbS2 for solar cell applications,” ACS Appl. Mater. Interfaces 9(48), 41916–41926 (2017).
43 P. Büttner, F. Scheler, C. Pointer, D. Döhler, M. K. S. Barr, A. Koroleva, D. Pankin, R. Hatada, S. Flege, A. Manshina, E. R. Young, I. Mínguez-Bacho, and J. Bachmann, “Adjusting interfacial chemistry and electronic properties of photovoltaics based on a highly pure Sb2S3 absorber by atomic layer deposition,” ACS Appl. Energy Mater. 2(12), 8747–8756 (2019).
44 Z. Deng, D. Chen, F. Tang, J. Ren, and A. J. Muscat, “Synthesis and purple-blue emission of antimony trioxide single-crystalline nanobelts with elliptical cross section,” Nano Res. 2(2), 151–160 (2009).
45 W. Shockley and H. J. Queisser, “Detailed balance limit of efficiency of p-n junction solar cells,” J. Appl. Phys. 32(3), 510–519 (1961).
46 Y. Qi, Y. Li, and Q. Lin, “Engineering the charge extraction and trap states of Sb2S3 solar cells,” Appl. Phys. Lett. 120(22), 221102 (2022).