Synthesis, Structure, Molecular Recognition, and Supramolecular Polymerization of Functionalized Feet-to-Feet Connected Bis- and Trisresorcinarenes

概要

Ꮫ఩ㄽᩥせ⣙
Synthesis, Structure, Molecular Recognition, and Supramolecular Polymerization of
Functionalized Feet-to-Feet Connected Bis- and Trisresorcinarenes
ᶵ⬟໬ࡉࢀࡓࣅࢫཬࡧࢺࣜࢫࣞࢰࣝࢩࣥ࢔࣮ࣞࣥࡢྜᡂᵓ㐀ศᏊㄆ㆑࡜㉸ศᏊ㔜ྜ㸧

ୗᒣ ኱㍜
Department of Chemistry, Graduate School of Science, Hiroshima University

Content of the thesis
Chapter 1 General Introduction
1.1 Macrocyclic hosts
1.2 Resorcinarenes
1.3 Cavitands
1.4 Overview of the Present Dissertation
1.5 References
Chapter 2 Synthesis of Feet-to-Feet Connected Bisresorcinarenes
2.1 Introduction
2.2 Synthesis of bisresorcinarenes
2.3 Crystal structures of bisresorcinarenes
2.4 Conclusion
2.5 Experimental Section
2.6 References
Chapter 3 Synthesis of Feet-to-Feet Connected Trisresorcinarenes
3.1 Introduction
3.2 Synthesis of trisresorcinarenes
3.3 Crystal structures of trisresorcinarenes
3.4 Conclusion
3.5 Experimental Section
3.6 References
Chapter

4

Conformational

Characteristics

of

Feet-to-Feet

Bisresorcinarenes and Biscavitands
4.1 Introduction
4.2 Synthesis of bisresorcinarenes and biscavitands
4.3 Crystal structures of bisresorcinarenes and biscavitands
4.4 Conformational characteristics of bisresorcinarenes
4.5 Conformational characteristics of functionalized bisresorcinarenes
4.6 Enthalpy–entropy compensation

Connected

4.7 Conclusion
4.8 Experimental Section
4.9 References
Chapter 5 Cooperativity in the Guest Binding of Biscavitands
5.1 Introduction
5.2 Synthesis of octaphosphonate biscavitand and guest molecules
5.3 Conformational characteristics of octaphosphonate biscavitands
5.4 Binding constants of the cooperative guest binding
5.5 A detail thermodynamic picture during the cooperative guest binding
5.6 Conclusion
5.7 Experimental Section
5.8 References
Chapter 6 Upper-rim Functionalization of Biscavitands
6.1 Introduction
6.2 Synthesis of functionalized biscavitands
6.3 Supramolecular polymerization of functionalized biscavitands
6.4 Conclusion
6.5 Experimental Section
6.6 References
Chapter 7 Helical Supramolecular Polymerization of Biscavitands
7.1 Introduction
7.2 Synthesis of monomer
7.3 Formation of the supramolecular polymer
7.4 Chiral induction of supramolecular polymer
7.5 Conclusion
7.6 Experimental Section
7.7 References
Acknowledment

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ࠕࡸࡴࢆᚓ࡞࠸஦⏤࡛ࠖㄽᩥࡀබ⾲࡛ࡁ࡞࠸ሙྜࡢࡳᥦฟࡋ࡚ࡃࡔࡉ࠸ࠋ
  ࠕࡸࡴࢆᚓ࡞࠸஦⏤ࠖࡀゎᾘࡉࢀࡓሙྜࡣ㸪ᣦᑟᩍဨࡢࢧ࢖ࣥࢆᚓ࡚,෌ᗘᥦฟࡋ࡚ࡃ
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