Geometric and Electronic Structures of Host-Guest Complex Ions Investigated by Cold Gas-Phase Spectroscopy
概要
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Geometric and Electronic Structures of Host–Guest Complex Ions Investigated
by Cold Gas-Phase Spectroscopy
㸦ᴟప ࣭Ẽ┦ศගἲࡼࡿ࣍ࢫࢺ㸫ࢤࢫࢺ㘒࢜ࣥࡢ❧యᵓ㐀㟁Ꮚ≧ែ㛵ࡍࡿ◊✲㸧
ᮌ⏣ ᇶ
Department of Chemistry, Graduate School of Science, Hiroshima University
Content of the thesis
Acknowledgements
Chapter 1 GENERAL INTRODUCTION
1.1 Host–Guest Chemistry
1.2 Crown Ether
1.3 Purpose and Outline of This Study
1.4 References
Chapter 2 EXPERIMENTAL & COMPUTATIONAL
2.1 Ultraviolet Photodissociation (UVPD) Spectroscopy
2.2 UV–UV Hole-Burning (HB) Spectroscopy
2.3 Quantum Chemical Calculations
2.4 References
Chapter 3 Dibenzo-Crown Ether Complexes with Alkali Metal Ions
3.1 Introduction
3.2 Experimental and Computational
3.3 Results and Discussion
3.3.1 UVPD Spectra and Structure of Dibenzo-CE Complexes
3.3.2 Fluorescence Spectra of Dibenzo-CE Complexes in Solution
3.4 Summary
3.5 References
Chapter 4 Protonated Dibenzylamine–Crown Ether Complexes ‘Pseudorotaxane’
4.1 Introduction
4.2 Experimental and Computational
4.3 Results and Discussion
4.3.1 Structure and Energetics of Bare dBAMH+
4.3.2 Structure and Energetics of dBAMH+–CE Complexes
Chapter 5 CONCLUDING REMARKS
Chapter 6 FURTHER RESULTS
6.1 UVPD Spectrum of dBAMH+–21C7 Complex
6.2 Structure of dBAMH+–21C7 Complex
6.3 1H NMR Spectra of dBAMH+–CE Complexes
6.4 Summary