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Supramolecular sulfur-containing polymers with hydrogen bonding

Kobayashi, Yuichiro 大阪大学

2023.03.03

概要

Sulfur is an abundant resource. Sulfur-containing polymers have attracted
attention as a alternatives to carbon polymers fabricated from exhaustible petroleum
resources.[1-4] Additionally, sulfur-containing polymers exhibit various properties not
observed in carbon polymers such as transparency and capacitance. Hence, sulfurcontaining polymers have potential in lenses and lithium-ion batteries.[5-7]
Although polysulfide polymers can be prepared by simply heating sulfur (S8),[8,9]
the obtained polysulfide polymers are unstable. They are prone to depolymerization
during the cooling process and exhibit a low solubility in common organic solvents. To
overcome these problems, a radical copolymerization method and a polycondensation
method have been developed.[10,11] The resultant sulfur-containing polymers are soluble
in common organic solvents. For example, a sulfur-containing polymer obtained by
copolymerization of S8 and styrene acquired the solubility derived from polystyrene and
were dissolved in chloroform (CHCl3), tetrahydrofuran (THF), and dimethyl sulfoxide
(DMSO). ...

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参考文献

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