飲料の選択的カフェイン吸着技術に関する研究 : 吸着剤による飲料中のカフェイン除去と飲料品質の両立

[1] Chang K. World tea production and trade: current and future development. Rome: Food and Agriculture Organization of the United Nations. 2015.

[2] World coffee consumption [Internet]. International Coffee Organization; 2016 Oct. Available from: http://www.ico.org/prices/new-consumption-table.pdf

[3] Khokhar S, Magnusdottir SGM. Total phenol, catechin, and caffeine content of teas commonly consumed in the United Kingdom. Journal of Agricultural and Food Chemistry. 2002; 50: 565-570.

[4] Perva-Uzunalić A, Škerget M, Knez Ž, Weinreich B, Otto F, Grüner S. Extraction of active ingredients from green tea (Camellia sinensis): Extraction efficiency of major catechins and caffeine. Food Chemistry. 2006; 96: 597-605.

[5] Yanagimoto K, Ochi H, Lee KG, Shibamoto T. Antioxidative activities of volatile extracts from green tea, oolong tea, and black tea. Journal of Agricultural and Food Chemistry. 2003; 51: 7396-7401.

[6] Hamilton-Miller JMT. Antimicrobial properties of tea (Camellia sinensis L.). Antimicrobial Agents and Chemotherapy. 1995; 39: 2375-2377.

[7] Suzuki M, Yoshino K, Maeda-Yamamoto M, Miyase T, Sano M. Inhibitory effects of tea catechins and O-methylated derivatives of (-)-epigallocatechin-3-O-gallate on mouse type IV allergy. Journal of Agricultural and Food Chemistry. 2000; 48: 5649-5653.

[8] Yoshino K, Yamazaki K, Sano M. Preventive effects of black tea theaflavins against mouse type IV allergy. Journal of the Science of Food and Agriculture. 2010; 90: 1983-1987.

[9] Matsumoto N, Ishigaki F, Ishigaki A, Iwashina H, Hara Y. Reduction of blood glucose levels by tea catechin. Bioscience, Biotechnology and Biochemistry. 1993; 57: 525-527.

[10] Toyoda-Ono Y, Yoshimura M, Nakai M, Fukui Y, Asami S, Shibata H, Kiso Y, Ikeda I. Suppression of postprandial hypertriglyceridemia in rats and mice by oolong tea polymerized polyphenols. Bioscience, Biotechnology and Biochemistry. 2007; 71: 971-976.

[11] Rains TM, Agarwal S, Maki KC. Antiobesity effects of green tea catechins: a mechanistic review. The Journal of Nutritional Biochemistry. 2011; 22: 1-7.

[12] Ueda M, Ashida H. Green tea prevents obesity by increasing expression of insulin-like growth factor binding protein-1 in adipose tissue of high-fat diet-fed mice. Journal of Agricultural and Food Chemistry. 2012; 60: 8917-8923.

[13] Uchiyama S, Taniguchi Y, Saka A, Yoshida A, Yajima H. Prevention of diet-induced obesity by dietary black tea polyphenols extract in vitro and in vivo. Nutrition. 2011; 27: 287-292.

[14] Ky CL, Louarn J, Dussert S, Guyot B, Hamon S, Noirot M. Caffeine, trigonelline, chlorogenic acids and sucrose diversity in wild Coffea arabica L. and C. canephora P. accessions. Food Chemistry. 2001; 75: 223-230.

[15] Del Castillo MD, Ames JM, Gordon MH. Effect of roasting on the antioxidant activity of coffee brews. Journal of Agricultural and Food Chemistry. 2002; 50: 3698-3703.

[16] Murase T, Yokoi Y, Misawa K, Ominami H, Suzuki Y, Shibuya Y, Hase T. Coffee polyphenols modulate whole-body substrate oxidation and suppress postprandial hyperglycaemia, hyperinsulinaemia and hyperlipidaemia. British Journal of Nutrition. 2012; 107: 1757-1765.

[17] Ochiai R, Sugiura Y, Shioya Y, Otsuka K, Katsuragi Y, Hashiguchi T. Coffee polyphenols improve peripheral endothelial function after glucose loading in healthy male adults. Nutrition Research. 2014; 34: 155-159.

[18] Tanaka K, Nishizono S, Tamaru S, Kondo M, Shimoda H, Tanaka J, Okada T. Anti-obesity and hypotriglyceridemic properties of coffee bean extract in SD rats. Food Science and Technology Research. 2009; 15: 147-152.

[19] McDougall B, King PJ, Wu BW, Hostomsky Z, Reinecke MG, Robinson WEJ. Dicaffeoylquinic and dicaffeoyltartaric acids are selective inhibitors of human immunodeficiency virus type 1 integrase. Antimicrobial Agents and Chemotherapy. 1998; 42: 140-146.

[20] BA ワインバーグ, BK ビーラー: カフェイン大全. 八坂書房. 2006. p. 22.

[21] Ashihara H, Sano H, Crozier A. Caffeine and related purine alkaloids: Biosynthesis, catabolism, function and genetic engineering. Phytochemistry. 2008; 69: 841-856.

[22] Naik JP, Nagalakshmi S. Determination of caffeine in tea products by an improved high-performance liquid chromatography method. Journal of Agricultural and Food Chemistry. 1997; 45: 3973-3975.

[23] Farah A. Coffee constituents. In: Chu YF, editor. Coffee: emerging health effects and disease prevention. Wiley-Blackwell; 2012. Chapter 2: p. 21-57.

[24] 文部科学省: 日本食品標準成分表 2015 年版（七訂）. 全国官報販売協同組合. 2015.

[25] Yamada M, Sasaki S, Murakami K, Takahashi Y, Okubo H, Hirota N, Notsu A, Todoriki H, Miura A, Fukui M, Date C. Estimation of caffeine intake in Japanese adults using 16 d weighed diet records based on a food composition database newly developed for Japanese populations. Public Health Nutrition. 2009; 13: 663-672.

[26] Weidner G, Istvan J. Dietary source of caffeine. The New England Journal of Medicine. 1985; 313: 1421.

[27] 渕之上康元, 渕之上弘子: 日本茶全書. 農文協. 1999. p. 164.

[28] Ramalakshmi K, Raghavan B. Caffeine in coffee: its removal. Why and how? Critical Reviews in Food Science and Nutrition. 1999; 39: 441-456.

[29] Vuong QV, Golding JB, Nguyen MH, Roach PD. Preparation of decaffeinated and high caffeine powders from green tea. Powder Technology. 2013; 233: 169-175.

[30] Huang KJ, Wu JJ, Chiu YH, Lai CY, Chang CMJ. Designed polar cosolvent-modified supercritical CO2 removing caffeine from and retaining catechins in green tea powder using response surface methodology. Journal of Agricultural and Food Chemistry. 2007; 55: 9014-9020.

[31] Park HS, Choi HK, Lee SJ, Park KW, Choi SG, Kim KH. Effect of mass transfer on the removal of caffeine from green tea by supercritical carbon dioxide. Journal of Supercritical Fluids. 2007; 42: 205-211.

[32] Tang WQ, Li DC, Lv YX, Jiang JG. Extraction and removal of caffeine from green tea by ultrasonic-enhanced supercritical fluid. Journal of Food Science. 2010; 75: 363-368.

[33] Kanda H, Li P, Makino H. Production of decaffeinated green tea leaves using liquefied dimethyl ether. Food and Bioproducts Processing. 2013; 91: 376-380.

[34] Kats SN. Coffee: Volume 2: Technology: Decafeination of Coffee. London: Elsevier Applied Science publishers. 1987. p. 59-71.

[35] Bichsel B. Diffusion phenomena during the decaffeination of coffee beans. Food Chemistry. 1979; 4: 53-62.

[36] Zosel K. Separation with supercritical gases: practical applications. Angewandte Chemie International Edition in English. 1978; 17: 702-709.

[37] Udayasankar K, Manohar B, Chokkalingam A. A note on supercritical carbon dioxide decaffeination of coffee. Journal of Food Science and Technology. 1986; 23: 326-328.

[38] Ye JH, Liang YR, Jin J, Liang HL, Du YY, Lu JL, Ye Q, Lin C. Preparation of partially decaffeinated instant green tea. Journal of Agricultural and Food Chemistry. 2007; 55: 3498-3502.

[39] Sakanaka S. A novel convenient process to obtain a raw decaffeinated tea polyphenol fraction using a lignocellulose column. Journal of Agricultural and Food Chemistry. 2003; 51: 3140-3143.

[40] Ye JH, Jin J, Liang HL, Lu JL, Du YY, Zheng WQ, Liang YR. Using tea stalk lignocellulose as an adsorbent for separating decaffeinated tea catechins. Bioresource Technology. 2009; 100: 622-628.

[41] Lu JL, Wu MY, Yang XL, Dong ZB, Ye JH, Borthakur D, Sun QL, Liang YR. Decaffeination of tea extracts by using poly(acrylamide-co-ethylene glycol dimethylacrylate) as adsorbent. Journal of Food Engineering. 2010; 97: 555-562.

[42] Sevillano DM, Van Der Wielen LAM, Hooshyar N, Ottens M. Resin selection for the separation of caffeine from green tea catechins. Food and Bioproducts Processing. 2014; 92: 192-198.

[43] Birtigh A, Liu K, Johannsen M, Brunner G. Regeneration methods for caffeine-loaded CO2. Separation Science and Technology. 1995; 30: 3265-3286.

[44] Lee S, Park MK, Kim KH, Kim YS. Effect of supercritical carbon dioxide decaffeination on volatile components of green teas. Journal of Food Science. 2007; 72: 497-502.

[45] Lee SM, Lee HS, Kim KH, Kim KO. Sensory characteristics and consumer acceptability of decaffeinated green teas. Journal of Food Science. 2009; 74: 135-141.

[46] Farah A, De Paulis T, Moreira DP, Trugo LC, Martin PR. Chlorogenic acids and lactones in regular and water-decaffeinated arabica coffees. Journal of Agricultural and Food Chemistry. 2006; 54: 374-381.

[47] Machmudah S, Kitada K, Sasaki M, Goto M, Munemasa J, Yamagata M. Simultaneous extraction and separation process for coffee beans with supercritical CO2 and water. Industrial & Engineering Chemistry Research. 2011; 50: 2227-2235.

[48] Kato M, Mizuno K, Crozier A, Fujimura T, Ashihara H. Caffeine synthase gene from tea leaves. Nature. 2000; 4062: 956-957.

[49] 芦原坦. カフェインフリーのチャやコーヒーの木をつくる!? 化学と生物. 2001; 39: 74-76.

[50] Ogino A, Tanaka J, Taniguchi F, Yamamoto MP, Yamada K. Detection and characterization of caffeine-less tea plants originated from interspecific hybridization. Breeding Science. 2009; 59: 277-283.

[51] 栗原久: カフェインの科学. 学会出版センター. 2004. p. 146-147.

[52] 日本粘土学会: 粘土ハンドブック（第三版）. 技報堂出版. 2009. p. 3.

[53] Brigatti MF, Galan E, Theng BKG. Handbook of clay science, edited by Bergaya F, Theng BKG, Lagaly G: Development in Clay Science, Volume 1: Structure and mineralogy of clay minerals. Amsterdam: Elsevier. 2006. p. 42-45.

[54] 白水晴雄: 粘土鉱物学. 朝倉書店. 1988. p. 11-35.

[55] 佐藤孝俊, 石田達也: 香粧品科学. 朝倉書店. 1997. p. 116-122.

[56] 上原茂胤, 広川昭夫. 活性白土の性能と原土との関係. 工業化学雑誌. 1955; 58: 174-177.

[57] 田中虔一, 田丸謙二: 触媒の科学. 産業図書. 1988. p. 192.

[58] 日本粉体工業技術協会: 造粒ハンドブック. オーム社. 1991. p. 629-656.

[59] 須藤談話会: 粘土科学への招待－粘土の素顔と魅力－. 三共出版. 2000. p. 292.

[60] Lee WF, Fu YT. Effect of montmorillonite on the swelling behavior and drug-release behavior of nanocomposite hydrogels. Journal of Applied Polymer Science. 2003; 89: 3652-3660.

[61] Joshi GV, Patel HA, Kevadiya BD, Bajaj HC. Montmorillonite intercalated with vitamin B1 as drug carrier. Applied Clay Science. 2009; 45: 248-253.

[62] González-Pradas E, Villafranca-Sánchez M, Gallego-Campo A. Influence of the physical-chemistry properties of an acid-activated bentonite in the bleaching of olive oil. Journal of Chemical Technology and Biotechnology. 1993; 57: 213-216.

[63] Tajchakavit S, Boye JI, Couture R. Effect of processing on post-bottling haze formation in apple juice. Food Research International. 2001; 34: 415-424.

[64] Yildirim HK. Effects of fining agents on antioxidant capacity of red wines. Journal of Institute of Brewing. 2011; 117: 55-60.

[65] Sarma GK, Sengupta S, Bhattacharyya KG. Methylene blue adsorption on natural and modified clays. Separation and Science Technology. 2011; 46: 1602-1614.

[66] Ogawa M, Ishii T, Miyamoto N, Kuroda K. Intercalation of a cationic azobenzene into montmorillonite. Applied Clay Science. 2003; 22: 179-185.

[67] Okada T, Seki Y, Ogawa M. Designed nanostructures of clay for controlled adsorption of organic compounds. Journal of Nanoscience and Nanotechnology. 2014; 14: 2121-2134.

[68] Barbier F, Duc G, Petit-Ramel M. Adsorption of lead and cadmium ions from aqueous solution to the montmorillonite/water interface. Colloids and Surfaces A: Physicochemical and Engineering Aspects. 2000; 166: 153-159.

[69] Hurel C, Marmier N, Bourg ACM, Fromage F. Sorption of Cs and Rb on purified and crude MX-80 bentonite in various electrolytes. Journal of Radioanalytical and Nuclear Chemistry. 2009; 279: 113-119.

[70] Gupta SS, Bhattacharyya KG. Adsorption of metal ions by clays and inorganic solids. RSC Advances. 2014; 4: 28537-28586.

[71] Russell JD, Cruz MI, White JL. Adsorption of 3-aminotriazole by montmorillonite. Journal of Agricultural and Food Chemistry. 1968; 16: 21-24.

[72] Aharonson N, Kafkafi U. Adsorption of benzimidazole fungicides on montmorillonite and kaolinite clay surfaces. Journal of Agricultural and Food Chemistry. 1975; 23: 434-437.

[73] Bradley WF. Molecular Associations between Montmorillonite and Some Polyfunctional Organic Liquids. Journal of the American Chemical Society. 1945; 67: 975-981.

[74] Yamanaka S, Kanamaru F, Koizumi M. Orientation of acrylonitrile adsorbed on interlamellar surfaces of montmorillonites. The Journal of Physical Chemistry. 1975; 79: 1285-1288.

[75] Marçal L, De Faria EH, Nassar EJ, Trujillano R, Martin N, Vicente MA, Rives V, Gil A, Korili SA, Ciuffi KJ. Organically modified saponites: SAXS study of swelling and application in caffeine removal. ACS Applied and Material Interfaces. 2015; 7: 10853-10862.

[76] Yamamoto K, Shiono T, Matsui Y, Yoneda M. Changes the structure and caffeine adsorption property of calcined montmorillonite. International Journal of GEOMATE. 2016; 11: 2301-2306.

[77] Norrish K. The swelling of montmorillonite. Discussions of the Faraday Society. 1954; 18: 120-134.

[78] Sato T, Watanabe T, Otsuka R. Effects of layer charge, charge location, and energy change on expansion properties of dioctahedral smectaites. Clays and Clay Minerals. 1992; 40: 103-113.

[79] Volzone C, Ortiga J. Influence of the exchangeable cations of montmorillonite on gas adsorptions. Process Safety and Environmental Protection. 2004; 82: 170-174.

[80] 栗原久. 日常生活の中におけるカフェイン摂取. 東京福祉大学・大学院紀要. 2016; 6: 109-125.

[81] 栗原久: カフェインの科学. 学会出版センター. 2004. p. 47-49.

[82] Blanchard J, Sawers SJ. The absolute bioavailability of caffeine in man. European Journal of Clinical Pharmacology. 1983; 24: 93-98.

[83] Weathersbee PS, Lodge JR. Caffeine: Its direct and indirect influence on reproduction. The Journal of Reproductive Medicine. 1977; 19: 55-63.

[84] Arnaud M. Caffeine, Coffee and Health, edited by Garattini S: Metabolism of caffeine and other components of coffee. New York: Raven Press. 1993. p. 43-95.

[85] Tang-Liu DD, Williams RL, Riegelman S. Disposition of caffeine and its metabolites in man. Journal of Pharmacology and Experimental Therapeutics. 1983; 224: 180-185.

[86] Aldridge A, Bailey J, Neims AH. The disposition of caffeine during and after pregnancy. Seminars in Perinatology. 1981; 5: 310-314.

[87] Knutti R, Rothweiler H, Schlatter C. The effect of pregnancy on the pharmacokinetics of caffeine. Archives of Toxicology. Supplement. 1982; 5: 187-192.

[88] Balogh A, Henschel L, Klinger G, Vollanth R, Börner A, Kuhnz W. Influence of ethinylestradiol-containing combination oral contraceptives with gestodene or levonorgestrel on caffeine elimination. European Journal of Clinical Pharmacology. 1995; 48: 161-166.

[89] Tsutsumi K, Kotegawa T, Matsuki S, Nakano S. T The effect of pregnancy on cytochrome P4501A2, xanthine oxidase, and N-acetyltransferase activities in humans. Clinical Pharmacology & Therapeutics. 2001; 70: 121-125.

[90] Tracy TS, Venkataramanan R, Glover DD, Caritis SN. Temporal changes in drug metabolism (CYP1A2, CYP2D6 and CYP3A activity) during pregnancy. American Journal of Obestetrics and Gynecology. 2005; 192: 633-639.

[91] Ginsberg G, Hattis D, Russ A, Sonawane B. Physiologically based pharmacokinetic (PBPK) modeling of caffeine and theophylline in neonates and adults: implications for assessing children's risks from environmental agents. Journal of Toxicology and Environmental Health, Part A. 2004; 67: 297-329.

[92] Grosso LM, Triche EW, Belanger K, Benowitz NL, Holford TR, Bracken MB. Caffeine metabolites in umbilical cord blood, cytochrome P-450 1A2 activity, and intrauterine growth restriction. American Journal of Epidemiology. 2006; 163: 1035-1041.

[93] Aranda JV, Collinge JM, Zinman R, Watters G. Maturation of caffeine elimination in infancy. Archives of Disease in Childhood. 1979; 54: 946-949.

[94] Von Borstel RW. Biological effeets of caffeine: Metabolism. Food Technology. 1983; 37: 40-43.

[95] Tantcheva-Poor I, Zaigler M, Rietbrock S, Fuhr U. Estimation of cytochrome P-450 CYP1A2 activity in 863 healthy Caucasians using a saliva-based caffeine test. Pharmacogenetics. 1999; 9: 131-144.

[96] 栗原久: カフェインの科学. 学会出版センター. 2004. p. 53-55.

[97] BA ワインバーグ, BK ビーラー: カフェイン大全. 八坂書房. 2006. p. 354-362.

[98] Rieg T, Steigele H, Schnermann J, Richter K, Osswald H, Vallon V. Requirement of intact adenosine A1 receptors for the diuretic and natriuretic action of the methylxanthines theophylline and caffeine. Journal of Pharmacology and Experimental Therapeutics. 2005; 313: 403-409.

[99] Ferré S. An update on the mechanisms of the psychostimulant effects of caffeine. Journal of Neurochemistry. 2008; 105: 1067-1079.

[100] Aronsen L, Orvoll E, Lysaa R, Ravna AW, Sager G. Modulation of high affinity ATP-dependent cyclic nucleotide transporters by specific and non-specific cyclic nucleotide phosphodiesterase inhibitors. European Journal of Pharmacology. 2014; 745: 249-253.

[101] 若島恵介, 辛島光彦. うつ伏せ姿勢による昼休みの短時間仮眠の効果に関する研究. 産業保健人間工学研究. 2011; 13: 47-50.

[102] Palacios N, Gao X, McCullough ML, Schwarzschild MA, Shah R, Gapstur S, Ascherio A. Caffeine and risk of Parkinson disease in a large cohort of men and women. Movement Disorders. 2012; 27: 1276-1282.

[103] Arab L, Khan F, Lam H. Epidemiologic evidence of a relationship between tea, coffee, or caffeine consumption and cognitive decline. American Society of Nutrition Advances in Nutrition. 2013; 4: 115-122.

[104] Lorist MM, Tops M. Caffeine, fatigue, and cognition. Brain and Cognition. 2003; 53: 82-94.

[105] Doherty M, Smith PM. Effects of caffeine ingestion on rating of perceived exertion during and after exercise: a meta-analysis. Scandinavian Journal of Medicine. 2005; 15: 69-78.

[106] Ruusunen A, Lehto SM, Tolmunen T, Mursu J, Kaplan GA, Voutilainen S. Coffee, tea and caffeine intake and the risk of severe depression in middle-aged Finnish men: the Kuopio Ischaemic Heart Disease Risk Factor Study. Public Health Nutrition. 2010; 13: 1215-1220.

[107] 栗原久: カフェインの科学. 学会出版センター. 2004. p. 59-69.

[108] Landolt HP, Dijk DJ, Gaus SE, Borbely AA. Caffeine reduces low-frequency delta activity in the human sleep EEG. Neuropsychopharmacology. 1995; 12: 229-238.

[109] Hindmarch I, Rigney U, Stanley N, Quinlan P, Rycroft J, Lane J. A naturalistic investigation of the effects of day-long consumption of tea, coffee and water on alertness, sleep onset and sleep quality. Psychopharmacology. 2000; 149: 203-216.

[110] Robinson D, Gelaye B, Tadesse MG, Williams MA, Lemma S, Berhane Y. Daytime sleepiness, circadian preference, caffeine consumption and khat use among college students in Ethiopia. Journal of Sleep Disorders: Treatment & Care. 2013; 3(1).

[111] Nawrot P, Jordan S, Eastwood J, Rotstein J, Hugenholtz A, Feeley M. Effects of caffeine on human health. Food Additives & Contaminants. 2003; 20: 1-30.

[112] Childs E, de Wit H. Subjective, behavioral, and physiological effects of acute caffeine in light, nondependent caffeine users. Psychopharmacology. 2006; 185: 514-523.

[113] Nurminen ML, Niittynen L, Korpela R, Vapaatalo H. Coffee, caffeine and blood pressure: a critical review. European Journal of Clinical Nutrition. 1999; 53: 831-839.

[114] Mostofsky E, Schlaug G, Mukamal KJ, Rosamond WD, Mittleman MA. Coffee and acute ischemic stroke onset: the Stroke Onset Study. Neurology. 2010; 75: 1583-1588.

[115] Fernandes O, Sabharwal M, Smiley T, Pastuszak A, Koren G, Einarson T. Moderate to heavy caffeine consumption during pregnancy and relationship to spontaneous abortion and abnormal fetal growth: a meta-analysis. Reproductive Toxicology. 1998; 12: 435-444.

[116] 藤原佐枝子. 骨粗鬆症の予防 II.栄養 2.危険因子（1）栄養的因子（カフェイン,アルコール,喫煙）. Bone. 2006; 20: 465-468.

[117] Armstrong LE, Pumerantz AC, Roti MW, Judelson DA, Watson G, Dias JC, Sokmen B, Casa DJ, Maresh CM, Lieberman H, Kellogg M. Fluid, electrolyte, and renal indices of hydration during 11 days of controlled caffeine consumption. International Journal of Sport Nutrition and Exercise Metabolism. 2005; 15: 252-265.

[118] 食品安全委員会: ファクトシート（食品中のカフェイン）. 2011.

[119] 栗原久. コーヒー／カフェイン摂取と日常生活－妊婦、胎児、乳幼児、小児への影響－. 東京福祉大学・大学院紀要. 2017; 7: 77-83.

[120] 川杉知史, 小針清孝, 井上隆康, 斎藤むら子. 深夜勤におけるカフェイン摂取の効果. 人間工学. 2002; 38: 510-511.

[121] 大垣寿美子, 伊村祈年子. 高血圧自然発症ラット（SHR）に及ぼすカフェインを除去した緑茶抽出液経口投与の影響. 生活衛生. 1989; 33: 171-175.

[122] 山本（前田）万里, 長屋行昭, 三森孝, 山口優一, 堀江秀樹, 江間かおり, 鈴木昌文, 山内英樹, 藁科文雄, 水上裕造, 廣野久子, 物部真奈美. 低カフェイン処理機を用いて製造した「べにふうき」緑茶の化学成分変動と抗アレルギー活性への影響. 日本食品工学会誌. 2007; 8: 109-116.

[123] Unno K, Yamada H, Iguchi K, Ishida H, Iwao Y, Morita A, Nakamura Y. Anti-stress effect of green tea with lowered caffeine on humans: a pilot study. Biological and Pharmaceutical Bulletin. 2017; 40: 902-909.

[124] Dang VBH, Doan HD, Dang-Vu T, Lohi A. Equilibrium and kinetics of biosorption of cadmium (II) and copper (II) ions by wheat straw. Bioresource Technology. 2009; 100: 211-219.

[125] Ho YS, McKay G. Pseudo-second order model for sorption processes. Process Biochemistry. 1999; 34: 451-465.

[126] Clifford MN, Johnston KL, Knight S, Kuhnert N. Hierarchical scheme for LC-MSn identification of chlorogenic acids. Journal of Agricultural and Food Chemistry. 2003; 51: 2900-2911.

[127] Farah A, De Paulis T, Trugo LC, Martin PR. Effect of roasting on the formation of chlorogenic acids lactones in coffee. Journal of Agricultural and Food Chemistry. 2005; 53: 1505-1513.

[128] Kano F, Abe I, Kamaya H, Ueda I. Fractal model for adsorption on activated carbon surfaces: Langmuir and Freundlich adsorption. Surface Science. 2000; 467: 131-138.

[129] Langmuir I. The adsorption of gases on plane surface of glass, mica and platinum. Journal of the American Chemical Society. 1918; 40: 1361-1402.

[130] Gogoi P, Dutta NN, Rao PG. Adsorption of catechin from aqueous solutions on polymeric resins and activated carbon. Indian Journal of Chemical Technology. 2010; 17: 337-345.

[131] Suárez-Quiroz ML, Campos AA, Alfaro GV, González-Ríos O, Villeneuve P, Figueroa-Espinoza MC. Isolation of green coffee chlorogenic acids using activated carbon. Journal of Food Composition and Analysis. 2014; 33: 55-58.

[132] Kim WJ, Kim JD, Kim J, Oh SG, Lee YW. Selective caffeine removal from green tea using supercritical carbon dioxide extraction. Journal of Food Engineering. 2008; 89: 303-309.

[133] Tsujimura M. Isolation of new catechin, tea catechin II or gallo-catechin from green tea. Bulletin of the Agricultural Chemical Society of Japan. 1934; 10: 140-147.

[134] Oshima Y. Chemical studies on the tannin substance of formosan tea-leaves. Bulletin of the Agricultural Chemical Society of Japan. 1936; 12: 103-114.

[135] McIlvaine TC. A buffer solution for colorimetric comparison. The Journal of Biological Chemistry. 1921; 49: 183-186.

[136] Lailach GE, Thompson TD, Brindley GW. Absorption of pyrimidines, purines, and nuclepsides by Co-, Ni-, Cu-, and Fe(III)-montmorillonite (clay-organic studies XII). Clays and Clay Minerals. 1968; 16: 285-293.

[137] Chugh A, Khanal D, Walkling-Ribeiro M, Corredig M, Duizer L, Griffiths W. Change in color and volatile composition of skim milk processed with pulsed electric field and microfiltration treatments or heat pasteurization. Foods. 2014; 3: 250-268.

[138] Komatsu Y, Suematsu S, Hisanobu Y, Saigo H, Matsuda R, Hara K. Effects of pH and temperature on reaction kinetics of catechins in green tea infusion. Bioscience, Biotechnology and Biochemistry. 1993; 57: 907-910.

[139] Oszmianski J, Cheynier V, Moutounet M. Iron-catalyzed oxidation of (+)-catechin in model systems. Journal of Agricultural and Food Chemistry. 1996; 44: 1712-1715.

[140] Catarino S, Madeira M, Monteiro F, Rocha F, Curvelo-Garcia AS, De Sousa RB. Effect of bentonite characteristics on the elemental composition of wine. Journal of Agricultural and Food Chemistry. 2008; 56: 158-165.

[141] Vicente Rodriguez MA, Suarez Barrios M, Lopez Gonzalez JD, Banares Munoz MA. Acid activation of ferrous saponite (griffithite): physico-chemical characterization and surface area of the products obtained. Clays and Clay Minerals. 1994; 42: 724-730.

[142] Clarke RJ. Coffee: Volume 2: Technology: Roasting and Grinding. London: Elsevier Applied Science publishers. 1987. p. 86-87.

[143] Wang X, Lim LT. A kinetics and modeling study of coffee roasting under isothermal conditions. Food and Bioprocess Technology. 2014; 7: 621-632.

[144] Moon JK, Yoo HS, Shibamoto T. Role of roasting conditions in the level of chlorogenic acid content in coffee beans: correlation with coffee acidity. Journal of Agricultural and Food Chemistry. 2009; 57: 5365-5369.

[145] Ludwig IA, Mena P, Calani L, Cid C, Del Rio D, Lean MEJ, Crozier A. Variations in caffeine and chlorogenic acid contents of coffees: what drinking? Food & Function. 2014; 5: 1718-1726.

[146] Mazzafera P, Crozier A, Magalhães AC. Caffeine metabolism in Coffea arabica and other species of coffee. Phytochemistry. 1991; 30: 3913-3916.

[147] Astill C, Birch MR, Cacombe C, Humphrey PG, Martin PT. Factors affecting the caffeine and poluphenol contents of black and green tea infusions. Journal of Agricultural and Food Chemistry. 2001; 49: 5340-5347.

[148] 堀江秀樹, 木幡勝則. 各種緑茶中のシュウ酸含量とその味への寄与. 茶業研究報告. 2000; 89: 23-27.

[149] Doherty WOS, Crees OL, Senogles E. Polymeric additives' effect on crystallization of calcium oxalate scales. Crystal Research and Technology. 1995; 30: 791-800.

[150] Demadis KD, Leonard I. Green polymeric additives for calcium oxalate control in industrial water and process applications. Materials Performance. 2011; 50: 40-44.

[151] 堀江秀樹, 山内雄二, 木幡勝則. 緑茶の硬水浸出液に生じる白色沈殿. 日本食品科学工学会誌. 1998; 45: 364-367.

[152] 稲垣順一, 西川孝. 茶渋の生成とその成分について. 三重県工業研究所研究報告. 2010; 34: 169-173.

[153] Kovacevic L, Lu H, Lakshmanan Y. Urinary turbidity as a marker of crystallization: Is spectrophotometric assessment useful? International Urology and Nephrology. 2013; 45: 1009-1015.

[154] 塩川二朗: 第 2 版 機器分析のてびき. 化学同人. 1996. p. 55-72.

[155] Bragg WL. The diffraction of short electromagnetic waves by crystal. Proceedings of the Cambridge Philosophical Society. 1913; 17: 43-57.

[156] Xu YQ, Chen GS, Du QZ, Que F, Yuan HB, Yin JF. Sediments in concentrated green tea furing low-temperature storage. Food Chemistry. 2014; 149: 137-143.

[157] 小川政英. 酸性白土の化学と工業. Journal of the Society of Inorganic Materials, Japan. 2002; 9: 310-316.

[158] Xu YQ, Zhong XY, Yin JF Yuan HB, Tang P, Du QZ. The impact of Ca2+ combination with organic acids on green tea infusions. Food Chemistry. 2013; 139: 944-948.

[159] 北出かおる, 片山詔久, 桑江彰夫. 黒ゴマの FT-IR/ATR スペクトル法を用いた成分分析. 日本食品科学工学会誌. 2010; 57: 215-219.

[160] 吉田募. 層間陽イオンの共存状態に関する統計熱力学的検討. 粘土科学. 1979; 19: 1-9.

[161] Bray HJ, Redferm SAT, Clark SM. The kinetics of dehydration in Ca-montmorillonite: an in situ X-ray diffraction study. Mineralogical Magazine. 1998; 62: 647-656.

[162] 趙小夫, 浦野紘平, 小笠原貞夫. 湿潤状態におけるモンモリロナイト系粘土鉱物の性状. 日本化学会誌. 1989; 2: 209-215.

[163] Okada T, Oguchi J, Yamamoto K, Shiono T, Fujita M, Iiyama T. Organoclays in water cause expansion that facilitates caffeine adsorption. Langmuir. 2015; 31: 180-187.

[164] Yamamoto K, Shiono T, Matsui Y, Yoneda M. Interaction of caffeine with montmorillonite. Particulate Science and Technology. 2018; in press. (http://doi.org/10.1080/02726351.2017.1372825)

[165] Yamamoto K, Shiono T, Matsui Y, Yoneda M. Influence of hydrophilicity on adsorption of caffeine onto montmorillonite. Adsorption Science & Technology. 2018; 36: 967-981.

[166] Okada T, Yoshida T, Iiyama T. Kinetics of interlayer expansion of a layered silicate driven by caffeine intercalation in the water phase using transmission X-ray diffraction. The Journal of Physical Chemistry B. 2017; 121: 6919-6925.