リケラボ論文検索は、全国の大学リポジトリにある学位論文・教授論文を一括検索できる論文検索サービスです。

リケラボ 全国の大学リポジトリにある学位論文・教授論文を一括検索するならリケラボ論文検索大学・研究所にある論文を検索できる

リケラボ 全国の大学リポジトリにある学位論文・教授論文を一括検索するならリケラボ論文検索大学・研究所にある論文を検索できる

大学・研究所にある論文を検索できる 「非晶質炭酸マグネシウムの構造と炭酸マグネシウム水和物鉱物の結晶化プロセス」の論文概要。リケラボ論文検索は、全国の大学リポジトリにある学位論文・教授論文を一括検索できる論文検索サービスです。

コピーが完了しました

URLをコピーしました

論文の公開元へ論文の公開元へ
書き出し

非晶質炭酸マグネシウムの構造と炭酸マグネシウム水和物鉱物の結晶化プロセス

山本, 弦一郎 筑波大学 DOI:10.15068/0002005484

2022.11.18

概要

地球温暖化の対策として二酸化炭素回収・貯留(CCS)に注目が集まっている.CCS技術の一つにCO2の地中貯留があり,その中でもCO2を炭酸塩鉱物として固定する方法は,安定に長期間CO2を固定できる有力な方法と考えられている.炭酸マグネシウム水和物は地中貯留される主要な鉱物の一つであるが,炭酸マグネシウム水和物の場合は,最初に非晶質相炭酸マグネシウム(Amorphous Magnesium Carbonate; 略してAMC)が先駆物質として生成され,その後,炭酸マグネシウム水和物に変化する.また,AMCは炭酸マグネシウム水和物の熱分解過程においても形成されることが知られており,CO2の地中貯留技術においてAMCの性質を理解することは非常に重要である.しかしながら,AMCはその構造さえも未だに明らかになっておらず,AMCには未解明な部分が多く残されている.そこで,本研究は,1.AMCの構造に及ぼす生成温度の影響,2.炭酸マグネシウム水和物の結晶化に及ぼすアルカリ金属イオンの影響,3.炭酸マグネシウム水和物の熱分解過程における構造変化について明らかにすることを目的に行った.

 まず,20,60,80℃でAMCを生成し,2体相関分布関数(atomic Pair-Distribution Function, PDF)解析を行った.その結果,20,60,80℃で生成されたAMCのPDFパターンはすべて非常に類似したパターンを示し,AMCの構造に温度依存性は認められなかった.また,AMCがhydromagnesite(Mg5(CO3)4(OH)2·4H2O)(HMG)の近距離構造(HMG-type構造)と同一であることが明らかになった.本研究ではこのAMCの構造をAMC-Ⅰと呼ぶ.

 次に,出発物質にNa2CO3,K2CO3,Rb2CO3,Cs2CO3を用いてAMCを生成した.Na+イオンを含む水溶液からは,最初にAMC-Ⅰが生成され,続いてAMC-Ⅰとは異なる近距離構造のAMCが出現し,その後nesquehonite(MgCO3·3H2O)(NSQ)が結晶化した.本研究ではAMC-Iの後に出現したAMCの構造をAMC-Ⅱと呼ぶ.一方,Rb+イオンを含む水溶液からは,AMC生成直後からAMC-Ⅱが出現したが,その後NSQは出現せず,最終的には非晶質相と未知の結晶相が出現した.また,Cs+イオンを含む水溶液も,AMC-Ⅰに続きAMC-Ⅱが出現し,その後NSQは出現せず,最終的には非晶質相と未知の結晶相が出現した.したがって,アルカリ金属イオンはAMCの形成には影響を与えないが,長距離秩序構造の形成には決定的な影響を与えていることが分かった.

 最後に,NSQ,HMG,dypingite(Mg5(CO3)4(OH)2·5H2O)(DYP)の熱分解過程における構造変化を調べた.NSQ,HMG,DYPのすべての熱分解過程でAMCが出現した.しかし,NSQ,DYPでの熱分解過程で形成されたAMCは,AMC-Ⅰであったのに対し,HMGの熱分解過程で出現したAMCはAMC-Ⅰ,AMC-Ⅱのどちらとも異なるPDFパターンを示し,本研究ではこのAMCの構造をAMC-Ⅲと呼ぶ.本研究の結果から,AMCは幅広い温度範囲と様々なアルカリ金属イオンを含む水溶液中において多様な近距離構造を持つことが明らかになった.本研究の結果は,AMCはCO2地中貯留において,最良なターゲット物質になり得ることを示唆している.

この論文で使われている画像

参考文献

第一章

Back, M.E. and Mandarino, J.A. (2008) Fleischer's glossary of mineral species. Tucson: Mineralogical Record Inc. Baines, S.J. and Worden, R.H. (2004) Geological storage of carbon dioxide. The Geological Society of Londo 233(1-6).

Ballirano, P., De Vito, C., Ferrini, V. and Mignardi, S. (2010) The thermal behaviour and structural stability of nesquehonite, MgCO3.3H2O, evaluated by in situ laboratory parallel-beam X-ray powder diffraction: New constraints on CO2 sequestration within minerals. J Hazard Mater 178(1-3), 522-528.

Ballirano, P., De Vito, C., Mignardi, S. and Ferrini, V. (2013) Phase transitions in the MgCO2H2O system and the thermal decomposition of dypingite, Mg5(CO3)4(OH)2·5H2O: Implications for geosequestration of carbon dioxide. Chemical Geology 340, 59-67.

Beinlich, A. and Austrheim, H. (2012) In situ sequestration of atmospheric CO2 at low temperature and surface cracking of serpentinized peridotite in mine shafts. Chemical Geology 332-333, 32-44.

Bénézeth, P., Saldi, G.D., Dandurand, J.-L. and Schott, J. (2011) Experimental determination of the solubility product of magnesite at 50 to 200°C. Chemical Geology 286(1-2), 21-31.

Bhattacharjya, D., Selvamani, T. and Mukhopadhyay, I. (2011) Thermal decomposition of hydromagnesite. Journal of Thermal Analysis and Calorimetry 107(2), 439-445.

Botha, A. and Strydom, C.A. (2001) Preparation of a magnesium hydroxy carbonate from magnesium hydroxide. Hydrometallurgy 62, 175-183.

Chaka, A.M. and Felmy, A.R. (2014) Ab initio thermodynamic model for magnesium carbonates and hydrates. J Phys Chem A 118(35), 7469-7488.

Chang, C.Y., Yang, S.Y. and Chan, J.C.C. (2021) Solubility product of amorphous magnesium carbonate. Journal of the Chinese Chemical Society 68(3), 476-481.

Cheng, W.T., Li, Z.B. and Demopoulos, G.P. (2009) Effects of temperature on the preparation of magnesium carbonate hydrates by reaction of MgCl2 with Na2CO3. Chinese Journal of Chemical Engineering 17(4), 661-666.

Dasgupta, R. and Hirschmann, M.M. (2010) The deep carbon cycle and melting in Earth's interior. Earth and Planetary Science Letters 298(1-2), 1-13.

Di Lorenzo, F., Rodríguez-Galán, R.M. and Prieto, M. (2018) Kinetics of the solvent-mediated transformation of hydromagnesite into magnesite at different temperatures. Mineralogical Magazine 78(6), 1363-1372.

Egami, T. and Billinge, S.J.L. (2003) Underneath the bragg peaks: structural analysis of complex materials, pergamon, 422.

F.L.Sayles and W.S.Fyfe (1973) The crystallization of magnesite from aqueous solution. Geochimica et Cosmochimica Acta 37(1), 87-96.

Falkowski, P., Scholes, R.J., Boyle, E., Canadell, J., Canfield, D., Elser, J., Gruber, N., Hibbard, K., Hogberg, P., Linder, S., Mackenzie, F.T., Moore, B., 3rd, Pedersen, T., Rosenthal, Y., Seitzinger, S., Smetacek, V. and Steffen, W. (2000) The global carbon cycle: a test of our knowledge of earth as a system. Science 290(5490), 291-296.

Farhang, F., Oliver, T.K., Rayson, M., Brent, G., Stockenhuber, M. and Kennedy, E. (2016) Experimental study on the precipitation of magnesite from thermally activated serpentine for CO2 sequestration. Chemical Engineering Journal 303, 439-449.

Frost, R.L., Bahfenne, S., Graham, J. and Reddy, B.J. (2008) The structure of selected magnesium carbonate minerals – A near infrared and mid-infrared spectroscopic study. Polyhedron 27(9-10), 2069-2076.

Gale, J. (2004) Geological storage of CO2: What do we know, where are the gaps and what more needs to be done? Energy 29(9-10), 1329-1338.

Hänchen, M., Prigiobbe, V., Baciocchi, R. and Mazzotti, M. (2008) Precipitation in the Mg-carbonate system— effects of temperature and CO2 pressure. Chemical Engineering Science 63(4), 1012-1028.

Haurie, L., Fernández, A.I., Velasco, J.I., Chimenos, J.M., Lopez Cuesta, J.-M. and Espiell, F. (2006) Synthetic hydromagnesite as flame retardant. Evaluation of the flame behaviour in a polyethylene matrix. Polymer Degradation and Stability 91(5), 989-994.

Hopkinson, L., Kristova, P., Rutt, K. and Cressey, G. (2012) Phase transitions in the system MgO–CO2–H2O during CO2 degassing of Mg-bearing solutions. Geochimica et Cosmochimica Acta 76, 1-13.

Hopkinson, L., Rutt, K. and Cressey, G. (2008) The transformation of nesquehonite to hydromagnesite in the system CaO-MgO-H2O-CO2: An experimental spectroscopic study. The Journal of Geology 116(4), 387-400.

Isshiki, M., Irifune, T., Hirose, K., Ono, S., Ohishi, Y., Watanuki, T., Nishibori, E., Takata, M. and Sakata, M. (2004) Stability of magnesite and its high-pressure form in the lowermost mantle. Nature 427(6969), 60-63.

J.Davies, P. and B.Bubela (1973) The transformation of nesquehonite into hydromagnesite. Chemical Geology 12(4), 289-300.

Jauffret, G., Morrison, J. and Glasser, F.P. (2015) On the thermal decomposition of nesquehonite. Journal of Thermal Analysis and Calorimetry 122(2), 601-609.

Jensen, A.C.S., Imberti, S., Habraken, W.J.E.M. and Bertinetti, L. (2020) Small ionic radius limits magnesium water interaction in amorphous calcium/magnesium carbonates. The Journal of Physical Chemistry C 124(11), 6141-6144.

Jensen, A.C.S., Rodriguez, I., Habraken, W., Fratzl, P. and Bertinetti, L. (2018) Mobility of hydrous species in amorphous calcium/magnesium carbonates. Physical Chemistry Chemical Physics 20(29), 19682-19688.

Königsberger, E., Königsberger, L.-C. and Gamsjägera, H. (1999) Low-temperature thermodynamic model for the system Na2CO3−MgCO3−CaCO3−H2O. Geochimica et Cosmochimica Acta 63(19-20), 3105-3119.

Kristova, P., Hopkinson, L.J., Rutt, K.J., Hunter, H.M.A. and Cressey, G. (2014) Carbonate mineral paragenesis and reaction kinetics in the system MgO–CaO–CO2 –H2O in presence of chloride or nitrate ions at near surface ambient temperatures. Applied Geochemistry 50, 16-24.

Lanas, J. and Alvarez, J.I. (2004) Dolomitic lime: thermal decomposition of nesquehonite. Thermochimica Acta 421(1-2), 123-132.

Langmuir, D. (1965) Stability of carbonates in the system MgO−CO2–H2O. The Journal of Geology 73, 730-754.

Leung, D.Y.C., Caramanna, G. and Maroto-Valer, M.M. (2014) An overview of current status of carbon dioxide capture and storage technologies. Renewable and Sustainable Energy Reviews 39, 426-443.

Li, Q., Ding, Y., Yu, G.H., Li, C., Li, F.Q. and Qian, Y.T. (2003) Fabrication of light-emitting porous hydromagnesite with rosette-like architecture. Solid State Communications 125(2), 117-120.

Lokhorst, A. and Wildenborg, T. (2006) Introduction on CO2 Geological Storage - Classification of Storage Options. Oil & Gas Science and Technology 60(3), 513-515.

Lytle, F.W., Sayers, D.E. and Stern, E.A. (1975) Extended x-ray-absorption fine-structure technique. II. Experimental practice and selected results. Physical Review B 11(12), 4825-4835.

Martinez, I., Chamorro Peréz, E.M., Matas, J., Gillet, P. and Vidal, G. (1998) Experimental investigation of silicate- carbonate system at high pressure and high temperature. Journal of Geophysical Research: Solid Earth 103(B3), 5143-5163.

Masson-Delmotte, V., Zhai, P., Pirani, A., Connors, S.L., Péan, C., Berger, S., Caud, N., Chen, Y., Goldfarb, L., Gomis, M.I., Huang, M., Leitzell, K., Lonnoy, E., Matthews, J.B.R., Maycock, T.K., Waterfield, T., Yelekçi, O., Yu, R. and Zhou, B. (2021) IPCC, 2021: Summary for Policymakers. In: Climate Change 2021: The Physical Science Basis. Contribution of Working Group I to the Sixth Assessment Report of the Intergovernmental Panel on Climate Change. Cambridge University Press. In Press.

Matter, J.M., Broecker, W.S., Stute, M., Gislason, S.R., Oelkers, E.H., Stefánsson, A., Wolff-Boenisch, D., Gunnlaugsson, E., Axelsson, G. and Björnsson, G. (2009) Permanent Carbon Dioxide Storage into Basalt: The CarbFix Pilot Project, Iceland. Energy Procedia 1(1), 3641-3646.

Montes-Hernandez, G. and Renard, F. (2016) Time-Resolved in Situ Raman Spectroscopy of the Nucleation and Growth of Siderite, Magnesite, and Calcite and Their Precursors. Crystal Growth & Design 16(12), 7218- 7230.

Morgan, B., Wilson, S.A., Madsen, I.C., Gozukara, Y.M. and Habsuda, J. (2015) Increased thermal stability of nesquehonite (MgCO3·3H2O) in the presence of humidity and CO2: Implications for low-temperature CO2 storage. International Journal of Greenhouse Gas Control 39, 366-376.

Perchiazzi, N. and Merlino, S. (2006) The malachite-rosasite group: crystal structures of glaukosphaerite and pokrovskite. European Journal of Mineralogy 18(6), 787-792.

Pokrovsky, O.S., Schott, J. and Thomas, F. (1999) Processes at the magnesium-bearing carbonates solution interface. I. A surface speciation model for magnesite. Geochimica et Cosmochimica Acta 63(6), 863-880.

Qafoku, O., Dixon, D.A., Rosso, K.M., Schaef, H.T., Bowden, M.E., Arey, B.W. and Felmy, A.R. (2015) Dynamics of Magnesite Formation at Low Temperature and High pCO2 in Aqueous Solution. Environ Sci Technol 49(17), 10736-10744.

Radha, A.V., Fernandez-Martinez, A., Hu, Y., Jun, Y.-S., Waychunas, G.A. and Navrotsky, A. (2012) Energetic and structural studies of amorphous Ca1−xMgxCO3·nH2O (0⩽x⩽1). Geochimica et Cosmochimica Acta 90, 83- 95.

Radha, A.V. and Navrotsky, A. (2014) Direct Experimental Measurement of Water Interaction Energetics in Amorphous Carbonates MCO3 (M = Ca, Mn, and Mg) and Implications for Carbonate Crystal Growth. Crystal Growth & Design 15(1), 70-78.

Rohrbach, A. and Schmidt, M.W. (2011) Redox freezing and melting in the Earth's deep mantle resulting from carbon-iron redox coupling. Nature 472(7342), 209-212.

Saldi, G.D., Jordan, G., Schott, J. and Oelkers, E.H. (2009) Magnesite growth rates as a function of temperature and saturation state. Geochimica et Cosmochimica Acta 73(19), 5646-5657.

Sandengen, K., Josang, L.O. and Kaasa, B. (2008) Simple method for synthesis of magnesite (MgCO3). Industrial & Engineering Chemistry Research 47(4), 1002-1004.

Sawada, Y., Uematsu, K., Mizutani, N. and Kato, M. (1978) Thermal decomposition of hydromagnesite 4MgCO3 - Mg(OH)2 - 4H2O under different partial pressures of carbon dioxide. Thermochimica Acta 27(1-3), 45-59.

Solopova, N.A., Dubrovinsky, L., Spivak, A.V., Litvin, Y.A. and Dubrovinskaia, N. (2014) Melting and decomposition of MgCO3 at pressures up to 84 GPa. Physics and Chemistry of Minerals 42(1), 73-81.

T.Katsura and E.Ito (1990) Melting and subsolidus phase relations in the MgSiO3–MgCO3 system at high pressures: implications to evolution of the Earth’s atmosphere. Earth and Planetary Science Letters 99(1-2), 110-117.

Tanaka, J.y., Kawano, J., Nagai, T. and Teng, H. (2019) Transformation process of amorphous magnesium carbonate in aqueous solution. Journal of Mineralogical and Petrological Sciences 114(2), 105-109.

Vágvölgyi, V., Frost, R.L., Hales, M., Locke, A., Kristóf, J. and Horváth, E. (2008) Controlled rate thermal analysis of hydromagnesite. Journal of Thermal Analysis and Calorimetry 92, 893-897.

White, C.E., Henson, N.J., Daemen, L.L., Hartl, M. and Page, K. (2014) Uncovering the True Atomic Structure of Disordered Materials: The Structure of a Hydrated Amorphous Magnesium Carbonate (MgCO3·3D2O). Chemistry of Materials 26(8), 2693-2702.

Xiong, Y. and Lord, A.S. (2008) Experimental investigations of the reaction path in the MgO–CO2–H2O system in solutions with various ionic strengths, and their applications to nuclear waste isolation. Applied Geochemistry 23(6), 1634-1659.

Xu, J., Yan, C., Zhang, F., Konishi, H., Xu, H. and Teng, H.H. (2013) Testing the cation-hydration effect on the crystallization of Ca-Mg-CO3 systems. Proceedings of the National Academy of Sciences of the United States of America 110(44), 17750-17755.

Yang, J., Han, Y., Luo, J., Leifer, K., Strømme, M. and Welch, K. (2019) Synthesis and characterization of amorphous magnesium carbonate nanoparticles. Materials Chemistry and Physics 224, 301-307.

Zhang, Z., Zheng, Y., Ni, Y., Liu, Z., Chen, J. and Liang, X. (2006) Temperature- and pH-dependent morphology and FT-IR analysis of magnesium carbonate hydrates. The Journal of Physical Chemistry B 110(26), 12969- 12973.

第二章

Akao, M. and Iwai, S. (1977) The hydrogen bonding of hydromagnesite. Acta Crystallographica B33, 1273-1275.

Amemiya, K., Kitajima, Y., Ohta, T. and Ito, K. (1996) Design of a holographically recorded plane grating with a varied line spacing for a soft X-ray grazing incidence monochromator. Journal of Synchrotron Radiation 3, 282-288.

Ballirano, P., De Vito, C., Mignardi, S. and Ferrini, V. (2013) Phase transitions in the Mg–CO2–H2O system and the thermal decomposition of dypingite, Mg5(CO3)4(OH)2·5H2O: Implications for geosequestration of carbon dioxide. Chemical Geology 340, 59-67.

Cabaret, D., Sainctavit, P., Ildefonse, P. and Flank, A.-M. (1998) Full multiple scattering calculations of the X-ray absorption near edgestructure at the magnesium K-edge in pyroxene. American Mineralogist 83, 300-304.

Dien, L., Mingsheng, P. and Murata, T. (1999) Coordination and local structure of magnesium in silicate minerals and glasses; Mg K-edge XANES study. The Canadian Mineralogist 37, 199-206.

Farrow, C.L., Juhas, P., Liu, J.W., Bryndin, D., Bozin, E.S., Bloch, J., Proffen, T. and Billinge, S.J. (2007) PDFfit2 and PDFgui: computer programs for studying nanostructure in crystals. Journal of Physics: Condensed Matter 19(33), 335219.

Fernández, A.I., Chimenos, J.M., Segarra, M., Fernández, M.A. and Espiell, F. (2000) Procedure to obtain hydromagnesite from a MgO-containing residue. Kinetic Study. Industrial & Engineering Chemistry Research 39(10), 3653-3658.

Finch, A.A. and Allison, N. (2018) Coordination of Sr and Mg in calcite and aragonite. Mineralogical Magazine 71(5), 539-552.

Frisch, M.J., Trucks, G.W., Schlegel, H.B., Scuseria, G.E., Robb, M.A., Cheeseman, J.R., Scalmani, G., Barone, V., Petersson, G.A., Nakatsuji, H., Li, X., Caricato, M., Marenich, A., Bloino, J., Janesko, B.G., Gomperts, R., Mennucci, B., Hratchian, H.P., Ortiz, J.V., Izmaylov, A.F., Sonnenberg, J.L., Williams-Young, D., Ding, F., Lipparini, F., Egidi, F., Goings, J., Peng, B., Petrone, A., Henderson, T., Ranasinghe, D., Zakrzewski, V.G.,

Gao, J., Rega, N., Zheng, G., Liang, W., Hada, M., Ehara, M., Toyota, K., Fukuda, R., Hasegawa, J., Ishida, M., Nakajima, T., Honda, Y., Kitao, O., Nakai, H., Vreven, T., Throssell, K., J. A. Montgomery, J., Peralta, J.E., Ogliaro, F., Bearpark, M., Heyd, J.J., Brothers, E., Kudin, K.N., Staroverov, V.N., Keith, T., Kobayashi, R., Normand, J., Raghavachari, K., Rendell, A., Burant, J.C., Iyengar, S.S., Tomasi, J., Cossi, M., Millam, J.M., Klene, M., Adamo, C., Cammi, R., Ochterski, J.W., Martin, R.L., Morokuma, K., Farkas, O., Foresman, J.B. and Fox, D.J. (2016) Gaussian 09, Gaussian, Inc., Wallingford CT.

Gebauer, D., Gunawidjaja, P.N., Ko, J.Y., Bacsik, Z., Aziz, B., Liu, L., Hu, Y., Bergstrom, L., Tai, C.W., Sham, T.K., Eden, M. and Hedin, N. (2010) Proto-calcite and proto-vaterite in amorphous calcium carbonates. Angewandte Chemie International Edition in English 49(47), 8889-8891.

Giester, G., Lengauer, C.L. and Rieck, B. (2000) The crystal structure of nesquehonite, MgCO3·3H2O, from Lavrion, Greece. Mineralogy and Petrology 70, 153-163.

Hemmati, A., Shayegan, J., Sharratt, P., Yeo, T.Y., Bu, J. (2014) Solid products characterization in a multi-step mineralization process. Chemical Engineering Journal. 252, 210-219.

Hopkinson, L., Kristova, P., Rutt, K. and Cressey, G. (2012) Phase transitions in the system MgO–CO2–H2O during CO2 degassing of Mg-bearing solutions. Geochimica et Cosmochimica Acta 76, 1-13.

Jensen, A.C.S., Imberti, S., Habraken, W.J.E.M. and Bertinetti, L. (2020) Small ionic radius limits magnesium water interaction in amorphous calcium/magnesium carbonates. The Journal of Physical Chemistry C 124(11), 6141-6144.

Juhás, P., Davis, T., Farrow, C.L. and Billinge, S.J.L. (2013) PDFgetX3: a rapid and highly automatable program for processing powder diffraction data into total scattering pair distribution functions. Journal of Applied Crystallography 46(2), 560-566.

Kloprogge, J.T., Martens, W.N., Nothdurft, L., Duong, .LV., Webb, G.E. (2003) Low temperature synthesis and characterization of nesquehonite. Journal of Materials Science Letters 22(11), 825-829.

Montes-Hernandez, G. and Renard, F. (2016) Time-Resolved in Situ Raman Spectroscopy of the Nucleation and Growth of Siderite, Magnesite, and Calcite and Their Precursors. Crystal Growth & Design 16(12), 7218- 7230.

Morgan, B., Wilson, S.A., Madsen, I.C., Gozukara, Y.M. and Habsuda, J. (2015) Increased thermal stability of nesquehonite (MgCO3·3H2O) in the presence of humidity and CO2: Implications for low-temperature CO2 storage. International Journal of Greenhouse Gas Control 39, 366-376.

Radha, A.V., Fernandez-Martinez, A., Hu, Y., Jun, Y.-S., Waychunas, G.A. and Navrotsky, A. (2012) Energetic and structural studies of amorphous Ca1−xMgxCO3·nH2O (0⩽x⩽1). Geochimica et Cosmochimica Acta 90, 83- 95.

Ravel, B. and Newville, M. (2005) ATHENA, ARTEMIS, HEPHAESTUS: data analysis for X-ray absorption spectroscopy using IFEFFIT. Journal of Synchrotron Radiation 12(Pt 4), 537-541.

Robinson, K., Gibbs, G.V. and Ribbe, P.H. (1971) Quadratic elongation: A quantitative measure of distortion in coordination polyhedra. Science 172, 567-570.

Tanaka, J.y., Kawano, J., Nagai, T. and Teng, H. (2019) Transformation process of amorphous magnesium carbonate in aqueous solution. Journal of Mineralogical and Petrological Sciences 114(2), 105-109.

Trcera, N., Cabaret, D., Rossano, S., Farges, F., Flank, A.-M. and Lagarde, P. (2008) Experimental and theoretical study of the structural environment of magnesium in minerals and silicate glasses using X-ray absorption near-edge structure. Physics and Chemistry of Minerals 36(5), 241-257.

White, C.E., Henson, N.J., Daemen, L.L., Hartl, M. and Page, K. (2014) Uncovering the True Atomic Structure of Disordered Materials: The Structure of a Hydrated Amorphous Magnesium Carbonate (MgCO3·3D2O). Chemistry of Materials 26(8), 2693-2702.

Wong, J., George, G.N., Pickering, I.J., Rek, Z.U., Rowen, M., Tanaka, T., Via, G.H., Devries, B., Vaughan, D.E.W. and Brown, G.E. (1994) New Opportunities in Xafs Investigation in the 1-2-Kev Region. Solid State Communications 92(7), 559-562.

Zhang, Z., Zheng, Y., Ni, Y., Liu, Z., Chen, J. and Liang, X. (2006) Temperature- and pH-dependent morphology and FT-IR analysis of magnesium carbonate hydrates. The Journal of Physical Chemistry B 110(26), 12969- 12973.

第三章

Amemiya, K., Kitajima, Y., Ohta, T. and Ito, K. (1996) Design of a holographically recorded plane grating with a varied line spacing for a soft X-ray grazing incidence monochromator. Journal of Synchrotron Radiation 3, 282-288.

Aminu, M.D., Nabavi, S.A., Rochelle, C.A., and Manovic, V. (2017) A review of developments in carbon dioxide storage. Applied Energy 208, 1389−1419.

Bachu, S., Gunter, W.D., and Perkins, E.H. (1994) Aquifer disposal of CO2: Hydrodynamic and mineral trapping. Energy Conversion and Management 35, 269−279.

Back, M.E., and Mandarino, J.A. (2008) Fleischer's glossary of mineral species. Mineralogical Record Inc., Tucson. Ballirano, P., De Vito, C., Ferrini, V., and Mignardi, S. (2010) The thermal behaviour and structural stability of nesquehonite, MgCO3·3H2O, evaluated by in situ laboratory parallel-beam X-ray powder diffraction: New constraints on CO2 sequestration within minerals. Journal of Hazardous Materials 178, 522–528.

Ballirano, P., De Vito, C., Mignardi, S., and Ferrini, V. (2013) Phase transitions in the Mg-CO2-H2O system and the thermal decomposition of dypingite, Mg5(CO3)4(OH)2·5H2O: Implications for geosequestration of Carbon dioxide. Chemical Geology 340, 59–67.

Beinlich, A., and Austrheim, H. (2012) In situ sequestration of atmospheric CO2 at low temperature and surface cracking of serpentinized peridotite in mine shafts. Chemical Geology 332, 32−44.

Bhattacharjya, D., Selvamani, T., and Mukhopadhyay, I. (2012) Thermal decomposition of hydromagnesite. Journal of Thermal Analysis and Calorimetry 107, 439–445.

Cheng, W.T., Li, Z.B. and Demopoulos, G.P. (2009) Effects of temperature on the preparation of magnesium carbonate hydrates by reaction of MgCl2 with Na2CO3. Chinese Journal of Chemical Engineering 17(4), 661-666.

DECC. CCS roadmap - supporting deployment of carbon capture and storage in the UK, 2012

DePaolo, D.J., and Cole, D.R. (2013) Geochemistry of geologic carbon sequestration: An overview, in: Donald D.J., David C.R., Alexandra N., Ian B.C. (Eds.), Geochemistry of Geologic CO2 Sequestration. Reviews in Mineralogy and Geochemistry, Mineralogical Society of America, Washington, DC, 77, p. 1−14.

Di Lorenzo, F., Rodriguez-Galan, R.M., and Prieto, M. (2014) Kinetics of the solvent-mediated transformation of hydromagnesite into magnesite at different temperatures. Mineralogical Magazine 78, 1363−1372.

Farrow, C.L., Juhas, P., Liu, J.W., Bryndin, D., Bozin, E.S., Bloch, J., Proffen, T. and Billinge, S.J. (2007) PDFfit2 and PDFgui: computer programs for studying nanostructure in crystals. Journal of Physics: Condensed Matter 19(33), 335219.

Frost R.L., Bahfenne, S., Graham, J., and Reddy, B.J. (2008) The structure of selected magnesium carbonate minerals - A near infrared and mid-infrared spectroscopic study. Polyhedron, 27, 2069–2076.

Hänchen, M., Prigiobbe, V., Baciocchi, R., and Mazzotti, M. (2008) Precipitation in the Mg-carbonate system - effects of temperature and CO2 pressure. Chemical Engineering Science 63, 1012–1028.

Hopkinson, L., Kristova, P., Rutt, K., and Cressey, G. (2012) Phase transitions in the system MgO-CO2-H2O during CO2 degassing of Mg-bearing solutions. Geochimica et Cosmochimica Acta 76, 1–13.

Hunt, J.M. (1972) Distribution of carbon in crust of earth. American Association of Petroleum Geologists 56, 2273−2277.

Inayat, A., Knoke, I., Spiecker, E. and Schwieger, W. (2012) Assemblies of mesoporous FAU-type zeolite nanosheets. Angew Chem Int Ed Engl 51(8), 1962-1965.

Jauffret, G., Morrison, J., and Glasser, F.P. (2015) On the thermal decomposition of nesquehonite. Journal of Thermal Analysis and Calorimetry 122, 601-609.

Jensen, A.C.S., Birkedal, H. and Bertinetti, L. (2019) Co-incorporation of alkali metal ions during amorphous calcium carbonate precipitation and their stabilizing effect. Physical Chemistry Chemical Physics 21(24), 13230-13233.

Juhás, P., Davis, T., Farrow, C.L. and Billinge, S.J.L. (2013) PDFgetX3: a rapid and highly automatable program for processing powder diffraction data into total scattering pair distribution functions. Journal of Applied Crystallography 46(2), 560-566.

Kristova, P., Hopkinson, L.J., Rutt, K.J., Hunter, H.M.A., and Cressey, G. (2014) Carbonate mineral paragenesis and reaction kinetics in the system MgO-CaO-CO2-H2O in presence of chloride or nitrate ions at near surface ambient temperatures. Applied Geochemistry 50, 16–24.

Li, Q., Ding, Y., Yu, G.H., Li, C., Li, F.Q. and Qian, Y.T. (2003) Fabrication of light-emitting porous hydromagnesite with rosette-like architecture. Solid State Communications 125(2), 117-120.

Matter, J.M., Broecker, W.S., Stute, M., Gislason, S.R., Oelkers, E.H., Stefánsson, A., Wolff-Boenisch, D., Gunnlaugsson, E., Axelsson, G. and Björnsson, G. (2009) Permanent Carbon Dioxide Storage into Basalt: The CarbFix Pilot Project, Iceland. Energy Procedia 1(1), 3641-3646.

Musyoka, N.M., Petrik, L.F., Hums, E., Baser, H. and Schwieger, W. (2014) In situ ultrasonic diagnostic of zeolite X crystallization with novel (hierarchical) morphology from coal fly ash. Ultrasonics 54(2), 537-543.

Oelkers, E.H., Gislason, S.R., and Matter, J. (2008) Mineral carbonation of CO2. Elements 4, 333–337.

Perchiazzi, N., and Merlino, S. (2006) The malachite-rosasite group: crystal structures of glaukosphaerite and pokrovskite. European Journal of Mineralogy 18, 787–792.

Ravel, B. and Newville, M. (2005) ATHENA, ARTEMIS, HEPHAESTUS: data analysis for X-ray absorption spectroscopy using IFEFFIT. Journal of Synchrotron Radiation 12(Pt 4), 537-541.

Reeder, R.J. (1983) Crystal chemistry of the rhombohedral carbonates, in: Reeder, R.J. (Ed.), Carbonates: mineralogy and chemistry. Reviews in Mineralogy, Mineralogical Society of America, Washington, DC, 11, p. 1–47.

Ren, H.R., Chen, Z., Wu, Y.L., Yang, M.D., Chen, J., Hu, H.S., and Liu, J. (2014) Thermal characterization and kinetic analysis of nesquehonite, hydromagnesite, and brucite, using TG-DTG and DSC techniques. Journal of Thermal Analysis and Calorimetry 115, 1949–1960.

Rodriguez-Blanco, J.D., Shaw, S., and Benning, L.G. (2011) The kinetics and mechanisms of amorphous calcium carbonate (ACC) crystallization to calcite, via vaterite. Nanoscale 3, 265−271.

Ryu, K.S., Bae, M.N., Kim, Y. and Seff, K. (2004) Further crystallographic confirmation that Cs+ ions can occupy sodalite cavities and double six-rings. Crystal structure of fully dehydrated partially Cs+-exchanged zeolite

X, |Cs45Na47| [Si100Al92O384]-FAU. Microporous and Mesoporous Materials 71(1-3), 65-75.

Sanna, A., Uibu, M., Caramanna, G., Kuusik, R., and Maroto-Valer, M.M. (2014) A review of mineral carbonation technologies to sequester CO2. Chemical Society Reviews 43, 8049–8080.

Steefel, C. I., Molins, S., and Trebotich, D. (2013) Pore scale processes associated with subsurface CO2 injection and sequestration. in: Donald D.J., David C.R., Alexandra N., Ian B.C. (Eds.), Geochemistry of Geologic CO2 Sequestration. Reviews in Mineralogy and Geochemistry, Mineralogical Society of America, Washington, DC, 77, 259−303.

Tanaka, J., Kawano, J., Nagai, T., and Teng, H. (2019) Transformation process of amorphous magnesium carbonate in aqueous solution. Journal of Mineralogical and Petrological Sciences 114, 105−109.

Tobler, D.J., Blanco, J.D.R., Sorensen, H.O., Stipp, S.L.S., and Dideriksen, K. (2016) Effect of pH on amorphous calcium carbonate structure and transformation. Crystal Growth & Design 16, 4500−4508.

Wang, Y., Li, Z.B., and Demopoulos, G.P. (2008) Controlled precipitation of nesquehonite (MgCO3·3H2O) by the reaction of MgCl2 with (NH4)2CO3. Journal of Crystal Growth 310, 1220−1227.

White, C.E., Henson, N.J., Daemen, L.L., Hartl, M., and Page, K. (2014) Uncovering the true atomic structure of disordered materials: the structure of a hydrated amorphous magnesium carbonate (MgCO3·3D2O). Chemistry of Materials 26, 2693−2702.

Zhang, Z.P., Zheng, Y.J., Ni, Y.W., Liu, Z.M., Chen, J.P., and Liang, X.M. (2006) Temperature–and pH–dependent morphology and FT–IR analysis of magnesium carbonate hydrates. Journal of Physical Chemistry B, 110, 12969–12973.

第四章

Akao, M. and Iwai, S. (1977) The hydrogen bonding of hydromagnesite. Acta Crystallographica B33, 1273-1275.

Amemiya, K., Kitajima, Y., Ohta, T. and Ito, K. (1996) Design of a holographically recorded plane grating with a varied line spacing for a soft X-ray grazing incidence monochromator. Journal of Synchrotron Radiation 3, 282-288.

Back, M.E. and Mandarino, J.A. (2008) Fleischer's glossary of mineral species. Tucson: Mineralogical Record Inc. Ballirano, P., De Vito, C., Ferrini, V. and Mignardi, S. (2010) The thermal behaviour and structural stability of nesquehonite, MgCO3·3H2O, evaluated by in situ laboratory parallel-beam X-ray powder diffraction: New constraints on CO2 sequestration within minerals. J Hazard Mater 178(1-3), 522-528.

Ballirano, P., De Vito, C., Mignardi, S. and Ferrini, V. (2013) Phase transitions in the Mg-CO2-H2O system and the thermal decomposition of dypingite, Mg5(CO3)4(OH)2·5H2O: Implications for geosequestration of carbon dioxide. Chemical Geology 340, 59-67.

Beinlich, A. and Austrheim, H. (2012) In situ sequestration of atmospheric CO2 at low temperature and surface cracking of serpentinized peridotite in mine shafts. Chemical Geology 332-333, 32-44.

Bhattacharjya, D., Selvamani, T. and Mukhopadhyay, I. (2011) Thermal decomposition of hydromagnesite. Journal of Thermal Analysis and Calorimetry 107(2), 439-445.

Botha, A. and Strydom, C.A. (2001) Preparation of a magnesium hydroxy carbonate from magnesium hydroxide. Hydrometallurgy 62, 175-183.

Cabaret, D., Sainctavit, P., Ildefonse, P. and Flank, A.-M. (1998) Full multiple scattering calculations of the X-ray absorption near edgestructure at the magnesium K-edge in pyroxene. American Mineralogist 83, 300-304.

Dien, L., Mingsheng, P. and Murata, T. (1999) Coordination and local structure of magnesium in silicate minerals and glasses; Mg K-edge XANES study. The Canadian Mineralogist 37, 199-206.

Farrow, C.L., Juhas, P., Liu, J.W., Bryndin, D., Bozin, E.S., Bloch, J., Proffen, T. and Billinge, S.J. (2007) PDFfit2 and PDFgui: computer programs for studying nanostructure in crystals. J Phys Condens Matter 19(33), 335219.

Frost, R.L., Bahfenne, S., Graham, J. and Martens, W.N. (2008a) Thermal stability of artinite, dypingite and brugnatellite—Implications for the geosequestration of green house gases. Thermochimica Acta 475(1-2), 39-43.

Frost, R.L., Bahfenne, S., Graham, J. and Reddy, B.J. (2008b) The structure of selected magnesium carbonate minerals – A near infrared and mid-infrared spectroscopic study. Polyhedron 27(9-10), 2069-2076.

Frykstrand, S., Strietzel, C., Forsgren, J., Ångström, J., Potinc, V. and Strømme, M. (2014) Synthesis, electron microscopy and X-ray characterization of oxymagnesite, MgO·2MgCO3, formed from amorphous magnesium carbonate. CrystEngComm 16(47), 10837-10844.

Giester, G., Lengauer, C.L. and Rieck, B. (2000) The crystal structure of nesquehonite, MgCO3·3H2O, from Lavrion, Greece. Mineralogy and Petrology 70, 153-163.

Hänchen, M., Prigiobbe, V., Baciocchi, R. and Mazzotti, M. (2008) Precipitation in the Mg-carbonate system— effects of temperature and CO2 pressure. Chemical Engineering Science 63(4), 1012-1028.

Hattori, T., Sano-Furukawa, A., Arima, H., Komatsu, K., Yamada, A., Inamura, Y., Nakatani, T., Seto, Y., Nagai, T., Utsumi, W., Iitaka, T., Kagi, H., Katayama, Y., Inoue, T., Otomo, T., Suzuya, K., Kamiyama, T., Arai, M. and Yagi, T. (2015) Design and performance of high-pressure PLANET beamline at pulsed neutron source at J-PARC. Nuclear Instruments and Methods in Physics Research Section A: Accelerators, Spectrometers, Detectors and Associated Equipment 780, 55-67.

Haurie, L., Fernández, A.I., Velasco, J.I., Chimenos, J.M., Lopez Cuesta, J.-M. and Espiell, F. (2006) Synthetic hydromagnesite as flame retardant. Evaluation of the flame behaviour in a polyethylene matrix. Polymer Degradation and Stability 91(5), 989-994.

Hazen, R.M. (1976) Effects of temperature and pressure on the cell dimension and X-ray temperature factors of periclase. American Mineralogist 61(3-4), 266-271.

Hopkinson, L., Kristova, P., Rutt, K. and Cressey, G. (2012) Phase transitions in the system MgO–CO2–H2O during CO2 degassing of Mg-bearing solutions. Geochimica et Cosmochimica Acta 76, 1-13.

Jauffret, G., Morrison, J. and Glasser, F.P. (2015) On the thermal decomposition of nesquehonite. Journal of Thermal Analysis and Calorimetry 122(2), 601-609.

Jensen, A.C.S., Imberti, S., Habraken, W.J.E.M. and Bertinetti, L. (2020) Small Ionic Radius Limits Magnesium Water Interaction in Amorphous Calcium/Magnesium Carbonates. The Journal of Physical Chemistry C 124(11), 6141-6144.

Juhás, P., Davis, T., Farrow, C.L. and Billinge, S.J.L. (2013) PDFgetX3: a rapid and highly automatable program for processing powder diffraction data into total scattering pair distribution functions. Journal of Applied Crystallography 46(2), 560-566.

Koga, N. and Yamane, Y. (2008) Effect of mechanical grinding on the reaction pathway and kinetics of the thermal decomposition of hydromagnesite. Journal of Thermal Analysis and Calorimetry 93(3), 963-971.

Kristova, P., Hopkinson, L.J., Rutt, K.J., Hunter, H.M.A. and Cressey, G. (2014) Carbonate mineral paragenesis and reaction kinetics in the system MgO–CaO–CO2–H2O in presence of chloride or nitrate ions at near surface ambient temperatures. Applied Geochemistry 50, 16-24.

Lanas, J. and Alvarez, J.I. (2004) Dolomitic lime: thermal decomposition of nesquehonite. Thermochimica Acta 421(1-2), 123-132.

Larson, A.C. and Dreele, R.B.V. (2004) General Structure Analysis System, (GSAS). Los Alamos National Laboratory Report LAUR, 86–784.

Li, Q., Ding, Y., Yu, G.H., Li, C., Li, F.Q. and Qian, Y.T. (2003) Fabrication of light-emitting porous hydromagnesite with rosette-like architecture. Solid State Communications 125(2), 117-120.

Momma, K. and Izumi, F. (2011) VESTA 3 for three-dimensional visualization of crystal, volumetric and morphology data. Journal of Applied Crystallography 44(6), 1272-1276.

Nashar, B. (1965) Barringtonite - a New Hydrous Magnesium Carbonate from Barrington Tops New South Wales Australia. Mineralogical magazine and journal of the Mineralogical Society 34(268), 370-372.

Perchiazzi, N. and Merlino, S. (2006) The malachite-rosasite group: crystal structures of glaukosphaerite and pokrovskite. European Journal of Mineralogy 18(6), 787-792.

Raade, G. (1970) Dypingite, a new hydrous basic carbonate of magnesium, from norway. American Mineralogist 55(9-10), 1457-1465.

Radha, A.V., Fernandez-Martinez, A., Hu, Y., Jun, Y.-S., Waychunas, G.A. and Navrotsky, A. (2012) Energetic and structural studies of amorphous Ca1−xMgxCO3·nH2O (0⩽x⩽1). Geochimica et Cosmochimica Acta 90, 83-95.

Ravel, B. and Newville, M. (2005) ATHENA, ARTEMIS, HEPHAESTUS: data analysis for X-ray absorption spectroscopy using IFEFFIT. J Synchrotron Radiat 12(Pt 4), 537-541.

Ren, H., Chen, Z., Wu, Y., Yang, M., Chen, J., Hu, H. and Liu, J. (2013) Thermal characterization and kinetic analysis of nesquehonite, hydromagnesite, and brucite, using TG–DTG and DSC techniques. Journal of Thermal Analysis and Calorimetry 115(2), 1949-1960.

Sawada, Y., Uematsu, K., Mizutani, N. and Kato, M. (1978) Thermal decomposition of hydromagnesite 4MgCO3- Mg(OH)2-4H2O under different partial pressures of carbon dioxide. Thermochimica Acta 27(1-3), 45-59.

Toby, B.H. (2001) EXPGUI, a graphical user interface for GSAS. Journal of Applied Crystallography 34, 210-213.

Vágvölgyi, V., Frost, R.L., Hales, M., Locke, A., Kristóf, J. and Horváth, E. (2008) Controlled rate thermal analysis of hydromagnesite. Journal of Thermal Analysis and Calorimetry 92, 893-897.

Wang, M., Shi, G., Qin, J. and Bai, Q. (2018) Thermal behaviour of calcite-structure carbonates: a powder X-ray diffraction study between 83 and 618 K. European Journal of Mineralogy 30(5), 929-949.

White, C.E., Henson, N.J., Daemen, L.L., Hartl, M. and Page, K. (2014) Uncovering the True Atomic Structure of Disordered Materials: The Structure of a Hydrated Amorphous Magnesium Carbonate (MgCO3·3D2O). Chemistry of Materials 26(8), 2693-2702.

Wu, Z., Mottana, A., Marcelli, A., Natoli, C.R. and Paris, E. (1996) Theoretical analysis of X-ray absorption near- edge structure in forsterite, Mg2SiO4-Pbnm, and fayalite, Fe2SiO4-Pbnm, at room temperature and extreme conditions. Physics and Chemistry of Minerals 23(3), 193-204.

参考文献をもっと見る

全国の大学の
卒論・修論・学位論文

一発検索!

この論文の関連論文を見る