(1) Wang, Q.; Domen, K. Particulate Photocatalysts for LightDriven Water Splitting: Mechanisms, Challenges, and Design
Strategies. Chem. Rev. 2020, 120, 919−985.
(2) Kranz, C.; Wächtler, M. Characterizing photocatalysts for water
splitting: from atoms to bulk and from slow to ultrafast processes.
Chem. Soc. Rev. 2021, 50, 1407−1437.
(3) Takanabe, K. Addressing fundamental experimental aspects of
photocatalysis studies. J. Catal. 2019, 370, 480−484.
(4) An, L.; Onishi, H. Electron-Hole Recombination Controlled by
Doping Sites in Perovskite-Structured Photocatalysts: Sr-Doped
NaTaO3. ACS Catal. 2015, 5, 3196−3206.
(5) Yamakata, A.; Ishibashi, T.; Kato, H.; Kudo, A.; Onishi, H.
Photodynamics of NaTaO3 Catalysts for Efficient Water Splitting. J.
Phys. Chem. B 2003, 107, 14383−14387.
(6) Sudrajat, H.; Dhakal, D.; Kitta, M.; Sasaki, T.; Ozawa, A.; Babel,
S.; Yoshida, T.; Ichikuni, N.; Onishi, H. Electron Population and
Water Splitting Activity Controlled by Strontium Cations Doped in
KTaO3 Photocatalysts. J. Phys. Chem. C 2019, 123, 18387−18397.
(7) Yoshihara, T.; Katoh, R.; Furube, A.; Tamaki, Y.; Murai, M.;
Hara, K.; Murata, S.; Arakawa, H.; Tachiya, M. Identification of
Reactive Species in Photoexcited Nanocrystalline TiO2 Films by
Wide-Wavelength-Range (400−2500 nm) Transient Absorption
Spectroscopy. J. Phys. Chem. B 2004, 108, 3817−3823.
(8) Tang, J.; Durrant, J. R.; Klug, D. R. Mechanism of Photocatalytic
Water Splitting in TiO2. Reaction of Water with Photoholes,
Importance of Charge Carrier Dynamics, and Evidence for FourHole Chemistry. J. Am. Chem. Soc. 2008, 130, 13885−13891.
(9) Le Formal, F.; Pastor, E.; Tilley, S. D.; Mesa, C. A.; Pendlebury,
S. R.; Grätzel, M.; Durrant, J. R. Rate Law Analysis of Water
Oxidation on a Hematite Surface. J. Am. Chem. Soc. 2015, 137, 6629−
6637.
(10) Ma, Y.; Pendlebury, S. R.; Reynal, A.; Le Formal, F.; Durrant, J.
R. Dynamics of photogenerated holes in undoped BiVO4 photoanodes for solar water oxidation. Chem. Sci. 2014, 5, 2964−2973.
(11) Nakamura, R.; Nakato, Y. Primary Intermediates of Oxygen
Photoevolution Reaction on TiO2 (Rutile) Particles, Revealed by in
Situ FTIR Absorption and Photoluminescence Measurements. J. Am.
Chem. Soc. 2004, 126, 1290−1298.
(12) Sivasankar, N.; Weare, W. W.; Frei, H. Direct Observation of a
Hydroperoxide Surface Intermediate upon Visible Light-Driven Water
Oxidation at an Ir Oxide Nanocluster Catalyst by Rapid-Scan FT-IR
Spectroscopy. J. Am. Chem. Soc. 2011, 133, 12976−12979.
(13) Zhang, M.; de Respinis, M.; Frei, H. Time-resolved
observations of water oxidation intermediates on a cobalt oxide
nanoparticle catalyst. Nat. Chem. 2014, 6, 362−367.
(14) Herlihy, D. M.; Waegele, M. M.; Chen, X.; Pemmaraju, C. D.;
Prendergast, D.; Cuk, T. Detecting the oxyl radical of photocatalytic
water oxidation at an n-SrTiO3/aqueous interface through its
subsurface vibration. Nat. Chem. 2016, 8, 549−555.
(15) Zandi, O.; Hamann, T. W. Determination of photoelectrochemical water oxidation intermediates on haematite electrode
surfaces using operando infrared spectroscopy. Nat. Chem. 2016, 8,
778−783.
(16) Chen, T.; Ding, Q.; Wang, X.; Feng, Z.; Li, C. Mechanistic
Studies on Photocatalytic Overall Water Splitting over Ga2O3-Based
Photocatalysts by Operando MS-FTIR Spectroscopy. J. Phys. Chem.
Lett. 2021, 12, 6029−6033.
26404
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J. Phys. Chem. C 2021, 125, 26398−26405
The Journal of Physical Chemistry C
pubs.acs.org/JPCC
Article
UV-photoexcited, H-atom n-doped, and thermally reduced TiO2. J.
Phys. Chem. C 2012, 116, 4535−4544.
(38) Sezen, H.; Buchholz, M.; Nefedov, A.; Natzeck, C.; Heissler, S.;
Di Valentin, C.; Wöll, C. Probing electrons in TiO2 polaronic trap
states by IR-absorption: evidence for the existence of hydrogenic
states. Sci. Rep. 2015, 4, No. 3808.
(39) Savory, D. M.; McQuillan, A. J. IR spectroscopic behavior of
polaronic trapped electrons in TiO2 under aqueous photocatalytic
conditions. J. Phys. Chem. C 2014, 118, 13680−13692.
(40) Sezen, H.; Shang, H.; Bebensee, F.; Yang, C.; Buchholz, M.;
Nefedov, A.; Heissler, S.; Carbogno, C.; Scheffler, M.; Rinke, P.; et al.
Evidence for photogenerated intermediate hole polarons in ZnO. Nat.
Commun. 2015, 6, No. 6901.
(41) Bandaranayake, S.; Hruska, E.; Londo, S.; Biswas, S.; Baker, L.
R. Small polarons and surface defects in metal oxide photocatalysts
studied using XUV reflection−absorption spectroscopy. J. Phys. Chem.
C 2020, 124, 22853−22870.
(42) Shelton, J. L.; Knowles, K. E. Thermally Activated Optical
Absorption into Polaronic States in Hematite. J. Phys. Chem. Lett.
2021, 12, 3343−3351.
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