Flow synthesis of triptycene via triple cycloaddition of ynolate to benzyne

Iwata, Takayuki 岩田, 隆幸イワタ, タカユキ Yoshinaga, Tatsuro 吉永, 達郎ヨシナガ, タツロウ Shindo, Mitsuru 新藤, 充シンドウ, ミツル九州大学

2020.08.21

概要

Flow synthesis of triptycene was achieved using triple cycloaddition of ynolate to benzyne. Employing the borate-type benzyne precursor, side reactions triggered by the addition of alkyllithium to ben

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Flow synthesis of triptycene via triple cycloaddition of ynolate to benzyne

概要

この論文で使われている画像

関連論文

Construction of Tricyclic Nitrogen Heterocycles by Gold(I)‐Catalyzed Cascade Cyclization of Allenynes and Its Application to Polycyclic π‐Electron Systems

Construction of Seven-Membered Carbocycles via 8π Electrocyclic Reactions

1,2‐Carbopentafluorophenylation of Alkynes: The Metallomimetic Pull‐Push Reactivity of Tris(pentafluorophenyl)borane

Theoretical Study of the Mechanism of Palladium(0)‐Catalyzed Intramolecular [2+2+2] Cycloaddition of Ester‐Substituted Alkynes

Photo-on-Demand In Situ Synthesis of N-Substituted Trichloroacetamides with Tetrachloroethylene and Their Conversions to Ureas, Carbamates, and Polyurethanes

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大学

学位論文種類・取得年

言語

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Flow synthesis of triptycene via triple cycloaddition of ynolate to benzyne

概要

この論文で使われている画像

関連論文

Construction of Tricyclic Nitrogen Heterocycles by Gold(I)‐Catalyzed Cascade Cyclization of Allenynes and Its Application to Polycyclic π‐Electron Systems

Construction of Seven-Membered Carbocycles via 8π Electrocyclic Reactions

1,2‐Carbopentafluorophenylation of Alkynes: The Metallomimetic Pull‐Push Reactivity of Tris(pentafluorophenyl)borane

Theoretical Study of the Mechanism of Palladium(0)‐Catalyzed Intramolecular [2+2+2] Cycloaddition of Ester‐Substituted Alkynes

Photo-on-Demand In Situ Synthesis of N-Substituted Trichloroacetamides with Tetrachloroethylene and Their Conversions to Ureas, Carbamates, and Polyurethanes