第1章
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第2章
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第3章
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[12] H. Onishi, S. Takai, T. Yabutsuka, T. Yao, Synthesis and electrochemical properties of LATP-LLTO lithium ion conductive composites, Electrochemistry. 84 (2016) 967–970. https://doi.org/10.5796/electrochemistry.84.967
[13] S. Takai, T. Yabutsuka, T. Yao, Synthesis and ion conductiviyt enhancement in oxide- based solid electrolyte LLZ-LLTO and LATO-LLTO compsite (in Japanese), in:Technical Information Institute (Ed.), Dev. Technol. Mater. Fabr. Process Improv. Ion Conduct. All Solid State Batter., Technical Information Institute, Tokyo, 2017: pp. 74–80.
[14] J. Maier, Pushing nanoionics to the limits: charge carrier chemistry in extremely small systems, Chem. Mater. 26 (2014) 348–360. https://doi.org/10.1021/cm4021657
[15] S. Breuer, V. Pregartner, S. Lunghammer, H.M.R. Wilkening, Dispersed solid conductors: fast interfacial Li-ion dynamics in nanostructured LiF and LiF:γ-Al2O3 composites, J. Phys. Chem. C. 123 (2019) 5222–5230.https://doi.org/https://doi.org/10.1021/acs.jpcc.8b10978
[16] V. Gulino, M. Brighi, F. Murgia, P. Ngene, P. de Jongh, R. Černý, M. Baricco, Room- Temperature Solid-State Lithium-Ion Battery Using a LiBH4–MgO Composite Electrolyte, ACS Appl. Energy Mater. 4 (2021) 1228–1236 https://doi.org/10.1021/acsaem.0c025254.5. SummaryIn summary, the long-range tracer diffusion coefficients of pristine LATP and LATP – LaPO4 composite have been measured in the first time through the neutron radiography technique in the temperature range 300 ℃ to 500 ℃. While the tracer diffusion coefficients of LATP – LaPO4 is slightly higher than that of pristine LATP, the difference is smaller than that expected from the room-temperature conductivity. This is presumably due to the reduced Debye length of the space charge layer which results in an enhanced bulk diffusion contribution in this temperature range. For further precise discussion on the contribution of space charge layer, diffusion measurements should be carried out at lower temperatures where the enhancement effect from space charge layer is more signfinicant, such that the difference in tracer diffusion coefficients between composite and pritine LATP at these tempeartures can be verified. At near room temperatures, owing to the ralatively low lithium mobitliy, solid-state NMR experimens should be employed instead of NR to investigate the lithium diffusion behaviors in composite samples[51]. Nonetheless, it has been revealed that the long-range lithium diffusion in the LATP-based system which demonstrated their potential as solid-state electrolytes for All-Solid-State-Batteries. From HR-TEM and EDS results, the LaPO4 particles dispersed in LATP matrix have been directly observed. TEM images at LATP matrix / LaPO4 particle interface suggest an intimate contact that is attributed to the reaction between LATP precursor and LLTO during the sintering process. Such microstructural feature is essential for the formation of the space charge layer at the LATP matrix / LaPO4 particle interface.
第4章
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第5章
[1] H. Onishi, S. Takai, T. Yabutsuka, T. Yao, Synthesis and electrochemical properties of LATP-LLTO lithium ion conductive composites, Electrochemistry. 84 (2016) 967–970. https://doi.org/10.5796/electrochemistry.84.967.
[2] I. V Krasnikova, M.A. Pogosova, A.O. Sanin, K.J. Stevenson, Toward Standardization of Electrochemical Impedance Spectroscopy Studies of Li-Ion Conductive Ceramics, Chem. Mater. 32 (2020) 2232–2241.
[3] C.R. Mariappan, C. Yada, F. Rosciano, B. Roling, Correlation between micro-structural properties and ionic conductivity of Li1.5Al0.5Ge1.5(PO4)3 ceramics, J. Power Sources. 196 (2011) 6456–6464. https://doi.org/10.1016/j.jpowsour.2011.03.065.
[4] S. Breuer, V. Pregartner, S. Lunghammer, H.M.R. Wilkening, Dispersed solid conductors: fast interfacial Li-ion dynamics in nanostructured LiF and LiF: $γ$-Al2O3 composites, J. Phys. Chem. C. 123 (2019) 5222–5230.https://doi.org/https://doi.org/10.1021/acs.jpcc.8b10978.
[5] V. Epp, M. Wilkening, Motion of Li+ in nanoengineered LiBH4 and LiBH4: Al2O3 comparison with the microcrystalline form, ChemPhysChem. 14 (2013) 3706–3713.
[6] V. Gulino, M. Brighi, F. Murgia, P. Ngene, P. de Jongh, R. Černý, M. Baricco, Room- Temperature Solid-State Lithium-Ion Battery Using a LiBH4--MgO Composite Electrolyte, ACS Appl. Energy Mater. 4 (2021) 1228–1236.
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